辐射法制备蛋黄壳及中空结构的MIL-125衍生材料用于提高光催化产氢性能  

Fabrication for Improved Photocatalytic H_(2) Production Using γ-Ray Irradiation: Yolk-shell and Hollow Structures Derived from MIL-125

作　　者：邰晨 刘华蓉[1] 胡源[2] Chen Tai;Hua-rong Liu;Yuan Hu(CAS Key Laboratory of Soft Matter Chemistry,Department of Polymer Science and Engineering,University of Science and Technology of China,Hefei 230026,China;State Key Laboratory of Fire Science,University of Science and Technology of China,Hefei 230026,China)

机构地区：[1]中国科学技术大学高分子科学与工程系,中国科学院软物质化学重点实验室,合肥230026 [2]中国科学技术大学安全科学与工程系,火灾科学国家重点实验室,合肥230026

出　　处：《Chinese Journal of Chemical Physics》2023年第3期329-338,I0039-I0045,I0100,共18页化学物理学报（英文）

基　　金：supported by the National Natural Science Foundation of China(No.51373160).

摘　　要：本文通过辐射法成功地制备出MIL-125衍生的蛋黄壳结构的MIL-125/TiO_(2)/Pt/CdS和中空结构的TiO_(2)/Pt/CdS可见光催化剂.通过r射线还原反应中,金属有机框架材料被部分或完全水解为TiO_(2)纳米片,形成了蛋黄壳或中空的异质结构.在可见光照射下,蛋黄壳结构的MIL-125/TiO_(2)/Pt/CdS产氢速率为2.9835 mmol:g^(-1)·h^(-1),而中空结构的TiO_(2)/Pt/CdS的产氢速率为1.9342 mmol:g^(-1)·h^(-1),分别是纯CdS的7.9和5.1倍.该结构优异的光催化性能可归因于对太阳光的有效吸收和利用,中空及卵黄壳的多孔结构促进物质的转移传输,以及TiO_(2)纳米片、CdS和Pt纳米颗粒之间的紧密接触可以改善光生电子空穴对的分离.这项工作为使用γ射线辐射法合成金属有机框架材料衍生的可见光催化剂开辟了一种新方法.The yolk-shell MIL125/TiO_(2)/Pt/CdS and hollow TiO_(2)/Pt/CdS visible-light catalysts were successfully synthesized from MIL-125 byγ-ray irradiation.During the reduction process byγ-ray irradiation,metal organic frameworks are partially or completely hydrolyzed to TiO_(2) nanosheets,forming the unique yolk-shell or hollow structure.The hydrogen production rate is 2.9835 mmol·g−1·h−1 for yolk-shell structures and 1.9342 mmol·g−1·h−1 for hollow structures under visible-light illumination,which is 7.9 and 5.1 times higher than that of CdS,respectively.The excellent properties of these photocatalysts may be attributed to the effective absorption and utilization of the light,the porous yolk-shell or hollow structure derived from MIL-125 to facilitate mass transfer,and close contact among CdS nanoparticles,TiO_(2) nanosheets and Pt nanoparticles to improve the separation of electron-hole pairs.This research can provide a simple and new method for the construction of high efficiency photocatalysts derived from MOFs using theγ-ray irradiation.

关 键 词：γ射线辐射 金属-有机框架材料 卵黄壳 中空 可见光催化产氢 

分 类 号：O643.36[理学—物理化学] O644.1[理学—化学] TQ116.2[化学工程—无机化工]