均相钴催化氨硼烷的脱氢及转移氢化反应的研究进展  

Advance of Dehydrogenation and Transfer Hydrogenation of Ammonia-Borane Catalyzed by Homogeneous Cobalt Complexes

作　　者：刘双 邹亮华 王晓明[2] Liu Shuang;Zou Lianghua;Wang Xiaoming(School of Life Science and Health Engineering,Jiangnan University,Wuxi,Jiangsu 214122;State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032)

机构地区：[1]江南大学生命科学与健康工程学院,江苏无锡214122 [2]中国科学院上海有机化学研究所,金属有机化学国家重点实验室,上海200032

出　　处：《有机化学》2023年第5期1713-1725,共13页Chinese Journal of Organic Chemistry

基　　金：江苏省研究生科研与实践创新计划(No.SJCX22_1115)资助项目。

摘　　要：作为理想的化学储氢材料,氨硼烷的高效脱氢和转移氢化的研究已经引起了越来越多的重视.由于丰产金属具有价廉易得和生物兼容性好等优势,丰产金属均相催化氨基硼烷的脱氢及相关转化,是该领域的重要发展方向.主要综述了代表性的均相丰产金属钴络合物催化的氨基硼烷的脱氢和转移氢化的研究进展.As an ideal chemical hydrogen storage material,efficient dehydrogenation and transfer hydrogenation of ammonia borane has attracted increasing attention.Due to the advantages of cheap and easy availability and biocompatibility of earth-abundant metals,the development of homogeneous catalytic dehydrogenation and related transformation of ammonia borane with earth-abundant metals is a significant research topic in this field.Herein,the development of dehydrogenation and transfer hydrogenation of ammonia borane catalyzed by homogeneous cobalt complexes is reviewed.

关 键 词：氨硼烷 均相催化 钴络合物 脱氢 转移氢化 

分 类 号：O621.251[理学—有机化学]