1,4-氮硼杂芳环在有机和过渡金属催化中的应用  

Application of 1,4-Azaborines in Organic and Transition Metal Catalysis

作　　者：景科 张攀科[1] 徐森苗 Jing Ke;Zhang Panke;Xu Senmiao(Green Catalysis Center,and College of Chemistry,Zhengzhou University,Zhengzhou 450001;State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000)

机构地区：[1]郑州大学化学学院绿色催化中心,郑州450001 [2]中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,兰州730000

出　　处：《有机化学》2023年第5期1742-1750,共9页Chinese Journal of Organic Chemistry

摘　　要：总结了1,4-氮硼杂芳环在有机和过渡金属催化中的最新进展,涵盖三部分内容:一是简要介绍了1,4-氮硼杂芳环的发展历史;二是重点介绍了1,4-氮硼杂芳环作为有机小分子催化剂在光致氧化三芳基膦中的应用;三是详细阐述了1,4-氮硼杂芳环作为配体在钯催化的烯炔的立体选择性硼化反应中的应用.此外,对这一领域的未来发展进行了展望.The recent progress of 1,4-azaborines in organic and transition metal catalysis is summarized,which consists of three parts.The first part briefly describes the history of 1,4-azaborines,the second part emphasizes on the application of 1,4-azaborines as an organocatalyst in the aerobic photooxidation of triaryl phosphines,and the last part discribes the use of 1,4-azaborines as the ligand in palladium-catalyzed stereoselective borylation of enynes.The future direction of this field is also proposed.

关 键 词：1 4-氮硼杂芳环 过渡金属 光致氧化 有机催化 

分 类 号：O621.251[理学—有机化学]