聚稳丁腈橡胶的结构与性能研究  

Structure and Properties of Polymerization Stabilized Nitrile Rubber

作　　者：范永将[1] 高卫光[1] 李冬红[1] 李红春[1] 瞿金磊 杨荣浩 刘莉[2] FAN Yongjiang;GAO Weiguang;LI Donghong;LI Hongchun;QU Jinlei;YANG Ronghao;LIU Li(PetroChina Lanzhou Petrochemical Academy,Lanzhou 730060,China;Qingdao University of Science and Technology,Qingdao 266042,China;Sino-German College of Engineering,Qingdao University of Science and Technology,Qingdao 266042,China)

机构地区：[1]中国石油兰州石化公司研究院,甘肃兰州730060 [2]青岛科技大学高性能聚合物及成型技术教育部工程研究中心,山东青岛266042 [3]青岛科技大学中德工程学院,山东青岛266042

出　　处：《橡胶工业》2023年第7期505-509,共5页China Rubber Industry

基　　金：国家自然科学基金资助项目(51972185)。

摘　　要：研究聚稳丁腈橡胶DN3305(简称DN3305)生胶的微观结构以及胶料的性能,并与普通丁腈橡胶3305E(简称3305E)进行对比。结果表明:DN3305的分子结构与3305E差异不大,相对分子质量及其分布与3305E接近,玻璃化温度高于3305E;DN3305混炼胶的门尼粘度低于3305E混炼胶,硫化特性相近,加工性能较好;DN3305硫化胶的300%定伸应力和拉伸强度高于3305E硫化胶,在110℃×28 d热空气老化后DN3305硫化胶仍有一定的弹性,具有较好的耐热空气老化性能,耐油性能也较好。对于非耐低温的丁腈橡胶制品,可用聚稳丁腈橡胶替代普通丁腈橡胶以获得优异的耐高温性能。The microstructure of raw rubber and the properties of the compound of polymerization stabilized nitrile rubber DN3305(referred to as DN3305)were studied and compared with ordinary nitrile rubber 3305E(referred to as 3305E).The results showed that,the molecular structure of DN3305 was not much different from that of 3305E,the molecular weight and its distribution were close to 3305E,and the glass transition temperature of DN3305 was higher than that of 3305E.The Mooney viscosity of DN3305 compound was lower than that of 3305E compound,the vulcanization characteristics were similar,and the processability was better.The tensile stress at 300%elongation and tensile strength of the DN3305 vulcanizate were higher than those of the 3305E vulcanizate.After hot air aging at 110℃for 28 days,the DN3305 vulcanizate still had some elasticity,showing better hot air aging resistance,and its oil resistance was also better.For the nitrile rubber products which did not require good low-temperature performance,polymerization stabilized nitrile rubber could be used to replace ordinary nitrile rubber to achieve excellent high-temperature resistance.

关 键 词：聚稳丁腈橡胶 反应型防老剂 微观结构 耐热空气老化性能 耐油性能 

分 类 号：TQ333.7[化学工程—橡胶工业]