过氧化氢氧化苯羟基化制苯酚研究进展  

Research advance on hydroxylation of benzene to phenol with hydrogen peroxide

作　　者：曾菲 司翠青 张璐瑶 张丹 徐文彪[1] Zeng Fei;Si Cuiqing;Zhang Luyao;Zhang Dan;Xu Wenbiao*(School of Material Science and Engineering,Beihua University,Jilin 132013,Jilin,China)

机构地区：[1]北华大学材料科学与工程学院,吉林吉林132013

出　　处：《工业催化》2023年第6期1-14,共14页Industrial Catalysis

基　　金：国家自然科学基金青年基金项目(52000002);吉林省科技厅自然科学基金联合基金项目(YDZJ202101ZYTS037);大学生创新创业计划训练项目(202110201195)。

摘　　要：苯酚作为一种重要的工业原料,以H_(2)O_(2)为氧化剂氧化苯制苯酚已成为苯酚制备的重要途径。综述H_(2)O_(2)体系中铁基、铜基和钒基等单金属/多金属基以及非金属等非均相催化剂在苯羟基化制苯酚中的研究进展,着重讨论催化剂催化性能以及反应机理,为多相体系中催化剂的设计以及苯酚的制备提供新思路。The oxidation of benzene to phenol with H 2O 2 as oxidant has become an important way for production of phenol which is an important industrial raw material.The research progress on iron based-,copper based-,vanadium based-and other single metal/multi metals based-,and nonmetal based-heterogeneous catalysts in H 2O 2 system for benzene hydroxylation to phenol was reviewed.The catalytic performance and reaction mechanism were emphatically discussed,aiming to provide a fresh perspective for the design of catalysts and the preparation of phenol in heterogeneous system.

关 键 词：有机化学工程 苯酚 苯 过氧化氢 羟基化 非均相 

分 类 号：TQ426.94[化学工程] TQ243.12