Semiconductor Electrochemistry for Clean Energy Conversion and Storage  

作　　者：Bin Zhu Liangdong Fan Naveed Mushtaq Rizwan Raza Muhammad Sajid Yan Wu Wenfeng Lin Jung‑Sik Kim Peter D.Lund Sining Yun 

机构地区：[1]Jiangsu Provincial Key Laboratory of Solar Energy Science and Technology/Energy Storage Joint Research Center,School of Energy and Environment,Southeast University,Nanjing 210096,Jiangsu,China [2]Shenzhen Key Laboratory of New Lithium‑Ion Batteries and Mesoporous Materials,College of Chemistry and Environmental Engineering,Shenzhen University,Shenzhen 518060,Guangdong,China [3]Clean Energy Research Lab(CERL),Department of Physics,COMSATS University Islamabad,Lahore Campus,Lahore 54000,Pakistan [4]Engineering Research Center of Nano‑Geo Materials of Ministry of Education,Faculty of Materials Science and Chemistry,China University of Geosciences,Wuhan 430074,Hubei,China [5]Department of Chemical Engineering,School of Aeronautical,Automotive,Chemical and Materials Engineering,Loughborough University,Loughborough LE113TU,UK [6]Department of Aeronautical&Automotive Engineering,School of Aeronautical,Automotive,Chemical and Materials Engineering,Loughborough University,Loughborough LE113TU,UK [7]Department of Engineering Physics/Advanced Energy Systems,School of Science,Aalto University,00076 Aalto,Espoo,Finland [8]Functional Materials Laboratory(FML),School of Materials Science and Engineering,Xi’an University of Architecture and Technology,Xi’an 710055,Shaanxi,China

出　　处：《Electrochemical Energy Reviews》2021年第4期757-792,共36页电化学能源评论（英文）

基　　金：the National Natural Science Foundation of China(51772080,51672208,51774259,and 51402093);the Natural Science Foundation of Guangdong Province(2021A1515012356 and 2017A030313289);the project foundation from the Ministry of Education of Guangdong Province(2019KTSCX151);Shenzhen Government Plan of Science and Technology(JCYJ20180305125247308);the National Laboratory of Solid State Microstructures,Nanjing University,EPSRC(EP/I013229/1);Royal Society and Newton Fund(NAF\R1\191294);Key Program for International S&T Cooperation Projects of Shaanxi Province(2019JZ-20,2019KWZ-03)。

摘　　要：Semiconductors and the associated methodologies applied to electrochemistry have recently grown as an emerging field in energy materials and technologies.For example,semiconductor membranes and heterostructure fuel cells are new technological trend,which differ from the traditional fuel cell electrochemistry principle employing three basic functional components:anode,electrolyte,and cathode.The electrolyte is key to the device performance by providing an ionic charge flow pathway between the anode and cathode while preventing electron passage.In contrast,semiconductors and derived heterostructures with electron(hole)conducting materials have demonstrated to be much better ionic conductors than the conventional ionic electrolytes.The energy band structure and alignment,band bending and built-in electric field are all important elements in this context to realize the necessary fuel cell functionalities.This review further extends to semiconductor-based electrochemical energy conversion and storage,describing their fundamentals and working principles,with the intention of advancing the understanding of the roles of semiconductors and energy bands in electrochemical devices for energy conversion and storage,as well as applications to meet emerging demands widely involved in energy applications,such as photocatalysis/water splitting devices,batteries and solar cells.This review provides new ideas and new solutions to problems beyond the conventional electrochemistry and presents new interdisciplinary approaches to develop clean energy conversion and storage technologies.

关 键 词：Semiconductor electrochemistry Fuel cells Lithium-ion batteries Solar cells Built-in electric field Energy system integration 

分 类 号：O64[理学—物理化学]