基于硝基烯烃的Morita-Baylis-Hillman醋酸酯的合成研究  

The Synthesis of Morita-Baylis-Hillman Acetate of Nitroalkenes

作　　者：尹鹏轩 杨鹏 李雪锋[1] Yin Pengxuan;Yang Peng;Li Xuefeng(School of Chemistry and Environmental,Southwest Minzu University,Chengdu 610041,China)

机构地区：[1]西南民族大学化学与环境学院,四川成都610041

出　　处：《山东化工》2023年第9期1-4,共4页Shandong Chemical Industry

基　　金：四川省科技厅应用基础项目(2022NSFSC0628);西南民族大学中央高校基本科研业务费专项资金项目(校2021113)。

摘　　要：通过改进Morita-Baylis-Hillman反应的条件,成功合成多种基于硝基烯烃的Morita-Baylis-Hillman醋酸酯,其中杂环类官能化硝基烯烃也可以顺利地进行,产物经过^(1)H NMR和^(13)C NMR分析,确认结构准确无误。A variety of Morita-Baylis-Hillman acetate of nitroalkenes were successfully synthesized under the modified reaction conditions of Morita-Baylis-Hillman process.The acetate of heteroaromatic nitroolefins can also be successfully constructed.The structures of the products were unambiguously confirmed by^(1)H NMR and^(13)C NMR analysis.

关 键 词：Morita-Baylis-Hillman反应 硝基烯烃 醋酸酯 

分 类 号：TQ225.24[化学工程—有机化工]