Controlled Synthesis of Polymers  

作　　者：Jingshan Sun Jiazhen Yang Jianxun Ding 

机构地区：[1]Key Laboratory of Polymer Ecomaterials,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,5625 Renmin Street,Changchun,Jilin 130022,China [2]School of Applied Chemistry and Engineering,University of Science and Technology of China,96 Jinzhai Road,Hefei,Anhui 230026,China [3]Jilin Biomedical Polymers Engineering Laboratory,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,5625 Renmin Street,Changchun,Jilin 130022,China

出　　处：《Chinese Journal of Chemistry》2023年第10期1235-1248,共14页中国化学（英文版）

基　　金：supported by the National Key Research and Development Program(Nos.2022YFC2603500,2021YFC2400600);the National Natural Science Foundation of China(Nos.52273158,U21A2099,52022095,52073280,51973216);the Science and Technology Development Program of Jjilin Province(Nos.20220204018YY,20210509005RQ,20210504001GH,20200404182YY);the Special Project for City-Academy Scientific and Technological Innovation Cooperation of Changchun(No.21SH14);the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2019230).

摘　　要：Controlled synthesis is central to obtaining polymers with accurate structures and excellent performances.Recent research in the controlled synthesis of polymers has focused on optimizing monomers,initiation systems,and reaction conditions.The satisfactory sequence,topological structure,and dispersity have been achieved to satisfy the growing demand for functional polymers.This re-view summarizes the selection of monomers of various types and structures,the innovation of initiation systems,and the optimiza-tion of reaction conditions in the controlled synthesis of polymers and discusses their challenges and opportunities.

关 键 词：POLYMER Selection of monomer Innovation of initiation system Optimization of reaction condition Controlled synthesis strategy 

分 类 号：O62[理学—有机化学]