Chiral phosphoric acid-catalyzed regio- and enantioselective reactions of functionalized propargylic alcohols  

作　　者：Chenxiao Qian Meiwen Liu Jianwei Sun Pengfei Li 

机构地区：[1]Shenzhen Grubbs Institute and Department of Chemistry,Guangdong Provincial Key Laboratory of Catalysis,College of Science,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China [2]Department of Chemistry,The Hong Kong University of Science and Technology,Clear Water Bay,Kowloon,Hong Kong SAR,China

出　　处：《Organic Chemistry Frontiers》2022年第5期1234-1240,共7页有机化学前沿（英文）

基　　金：The authors acknowledge the financial support from the Shenzhen Innovation of Science and Technology Commission(20200925151614002);the Guangdong Provincial Key Laboratory of Catalysis(2020B121201002)。

摘　　要：Propargylic alcohols have been known as useful substrates in a wide range of asymmetric reactions.In particular,chiral phosphoric acid(CPA)catalyzed reactions of functionalized propargylic alcohols have opened robust access to axially chiral tetrasubstituted allenes and their related derivatives.

关 键 词：ALCOHOLS catalyzed CHIRAL 

分 类 号：O64[理学—物理化学]