Sharing the salt bowl: counterion identity drives N-alkyl resorcinarene affinity for pyrophosphate in water  

作　　者：Kwaku Twum Seyed Iraj Sadraei Jordan Feder S.Maryamdokht Taimoory Kari Rissanen John F.Trant Ngong Kodiah Beyeh 

机构地区：[1]Department of Chemistry,Oakland University,146 Library Drive,Rochester,MI 48309-4479,USA [2]Department of Chemistry and Biochemistry,University of Windsor,401 Sunset Avenue,Windsor,ON,N9B 3P4,Canada [3]University of Michigan,Department of Chemistry,Ann Arbor,MI,USA [4]University of Jyvaskyla,Department of Chemistry,P.O.Box 35,40014 Jyvaskyla,Finland

出　　处：《Organic Chemistry Frontiers》2022年第5期1267-1275,共9页有机化学前沿（英文）

基　　金：This work was funded in part by the Natural Sciences and Engineering Research Council of Canada(Grant#2018-06338 to JFT);the Windsor Cancer Centre Foundation Seeds4Hope Seed Grant Funding Program(Grant#2017-03 to JFT);an Ontario Early Researcher Award(Grant#ER18-14-114 to JFT).

摘　　要：N-Alkyl ammonium resorcinarene chloride receptors,NARX_(4),have been shown to act as high-sensitivity detectors of pyrophosphate(PPi),a biomarker of disease,in aqueous media through the chloride-to-PPi exchange[NAR(Cl)_(4) to NARPPi].

关 键 词：ALKYL ammonium exchange 

分 类 号：O62[理学—有机化学]