Samarium( II )-electrocatalyzed chemoselective reductive alkoxylation of phthalimides  

作　　者：Yu-Feng Zhang Mohamed Mellah 

机构地区：[1]Universite Paris-Saclay,CNRS,Institut de Chimie Moleculaire et des Materiaux d’Orsay,Batiment 420,91405 Orsay,France

出　　处：《Organic Chemistry Frontiers》2022年第5期1308-1314,共7页有机化学前沿（英文）

摘　　要：The unprecedented samarium electrocatalyzed reductive alkoxylation of phthalimides in a single step is presented.Under mild conditions,using electrogenerated Sm(II)with TMSCl(trimethyl chlorosilane),N-substituted 3-alkoxyl isoindolin-1-ones are isolated in good to excellent yields with high functional group tolerance.

关 键 词：catalyzed REDUCTIVE SUBSTITUTED 

分 类 号：O62[理学—有机化学]