苄位C-H键选择性氧化研究进展  

Research Progress on Selective Oxidation of Benzyl C-H Bonds

作　　者：李新 余志群 LI Xin;YU Zhiqun(Collaborative Innovation Center of Green Pharmaceuticals,Zhejiang University of Technology,Hangzhou,Zhejiang 310014,China)

机构地区：[1]浙江工业大学绿色制药协同创新中心,浙江杭州310014

出　　处：《浙江化工》2023年第6期16-22,共7页Zhejiang Chemical Industry

摘　　要：苄位C-H键选择性氧化是有机合成中一类重要的反应,其氧化产物广泛应用于化学合成的各个领域。传统的苄位C-H键氧化存在选择性差、转化率低、副产物多而杂、三废污染严重等缺点。随着化学工业不断进步,新的苄位C-H键选择性氧化的氧化方法和催化剂不断涌现。本文针对苄位C-H键选择性氧化的氧化方法进行综述。Selective oxidation of benzyl C-H bonds is an important reaction in organic synthesis,and its oxidation products are widely used in various fields of chemical synthesis.Traditional benzyl C-H bond oxidation has the disadvantages of poor selectivity,low conversion rate,many by-products and serious pollution of three wastes.With the continuous advancement of the chemical industry,new oxidation methods and catalysts for the selective oxidation of benzyl C-H bonds are emerging.This article reviews the oxidation methods for selective oxidation of benzyl C-H bonds.

关 键 词：苄位C-H键 选择性氧化 分子氧催化氧化 微生物催化氧化法 光催化氧化法 电解氧化法 化学试剂氧化法 

分 类 号：O621.251[理学—有机化学]