铁氮化工艺、氮化铁的性质及氧化行为的研究现状与展望  

Research Status and Prospect of Iron Nitriding Techniques,Properties and Oxidation Behavior of Iron Nitrides

作　　者：刘嘉琴 王晓方[1] 刘柯钊[1] LIU Jiaqin;WANG Xiaofang;LIU Kezhao(Science and Technology on Surface Physics and Chemistry Laboratory,Mianyang 621908,Sichuan,China)

机构地区：[1]表面物理与化学重点实验室,四川绵阳621908

出　　处：《材料导报》2023年第14期160-175,共16页Materials Reports

基　　金：国家自然科学基金(22172148)。

摘　　要：氮化铁作为一种典型的填隙合金,具有较为丰富的相结构、优良的抗腐蚀性及耐磨性、高的热稳定性,在铁及其合金的表面腐蚀防护领域具有重要的应用价值。本文系统地综述了铁表面氮化工艺的方法、工艺原理以及不同技术的优缺点,同时归纳了氮化铁薄膜材料的制备技术,包括气相沉积法、溅射法以及分子束外延法,并详细介绍了氮化铁的物相结构及其转化规律,最后重点对氮化铁的氧化行为及氧化模型研究进展进行总结,以期为氮化铁的实验研究和腐蚀防护应用提供参考。Iron nitrides with rich structures have attracted wide attention in the field of material surface corrosion protection due to their high thermal stability,excellent corrosion resistance and wear resistance.In this paper,the nitridation processing techniques and the related studies on the formation mechanism of the nitride layers,as well as the advantages and disadvantages of different technologies are systematically reviewed.At the same time,the preparation technologies of iron nitrides film materials,including vapor deposition,sputtering and molecular beam epitaxy,are summarized.Then the phase structure and its transition behavior are introduced in detail.Finally,the research progress of oxidation behavior and kinetic model of iron nitride are summarized in order to provide reference for experimental research and corrosion protection application of iron nitrides.

关 键 词：氮化铁 氮化工艺 氧化行为 动力学模型 

分 类 号：TG174.4[金属学及工艺—金属表面处理]