检索规则说明:AND代表“并且”;OR代表“或者”;NOT代表“不包含”;(注意必须大写,运算符两边需空一格)
检 索 范 例 :范例一: (K=图书馆学 OR K=情报学) AND A=范并思 范例二:J=计算机应用与软件 AND (U=C++ OR U=Basic) NOT M=Visual
作 者:Yong Lu Qiu Zhang Jun Chen
出 处:《CCS Chemistry》2023年第7期1491-1508,共18页中国化学会会刊(英文)
基 金:This work was supported by the National Key R&D Pro-gram of China(grant no.2022YFB2402200);the Nation-al Natural Science Foundation of China(grant nos.22109075,22121005,22020102002,and 21835004);Frontiers Science Center for New Organic Matter of Nankai University(grant no.63181206).
摘 要:Organic electrode materials have attracted much attention for lithium batteries because of their high capacity,flexible designability,and environmental friendliness.Understanding the redox chemistry of organic electrode materials is essential for optimizing electrochemical performance and designing new molecules.This review aims to summarize the redox chemistry of different organic electrode materials in lithium batteries,including carbonyl compounds,conductive polymers,organosulfur compounds,organic radicals,imine compounds,compounds with superlithiation ability,and azo compounds.The discussions are focused on the evolution of their molecular and crystal structures during discharge/charge processes utilizing various characterization approaches.To date,carbonyl compounds based on the conversion between C=O and C-OLi have been proven to be one of the most promising organic electrode materials for lithium batteries.Future works should pay more attention to the detection of redox intermediates through operando techniques and the further combination of theoretical calculations.This review provides insights into the redox chemistry of organic electrode materials in lithium batteries.
关 键 词:lithium batteries organic electrode materials redox chemistry INTERMEDIATES phase transitions
正在载入数据...
正在载入数据...
正在载入数据...
正在载入数据...
正在载入数据...
正在载入数据...
正在载入数据...
正在链接到云南高校图书馆文献保障联盟下载...
云南高校图书馆联盟文献共享服务平台 版权所有©
您的IP:216.73.216.249