双环化反应构建碳环骨架研究  

Study on the Construction of Carbocyclic Skeleton by Bicyclization

作　　者：范威 FAN Wei(Science and Technology Office,Chuzhou City Vocation College,Chuzhou 239000,China)

机构地区：[1]滁州城市职业学院科技处,安徽滁州239000

出　　处：《唐山师范学院学报》2023年第3期10-14,30,共6页Journal of Tangshan Normal University

基　　金：滁州城市职业学院横向课题(2021hxkt03)。

摘　　要：串联会聚性、成环连续性、成键有效性是双环化反应的显著特点,该类反应是高效构建碳环、氮杂环、氧杂环等骨架的常用方法,通过芳构化、偶联、环化等过程,可以构建茚、萘、环庚烯并环己烯酮等碳环骨架。Tandem convergence,continuity of ring formation and effectiveness of bond formation are the remarkable characteristics of bicyclization reactions,which are commonly used to efficiently construct carboncyclic,nitrogen heterocycle,oxygen heterocycle and other skeletons.This paper reports the research on the efficient and highly selective synthesis of carbocyclic compounds based on bicyclization reaction,through aromatization,coupling,cyclization and other processes.The construction of the carbocyclic skeleton of indenes,naphthalenes,cycloheptanocyclohexenones are realized.

关 键 词：双环化 碳环骨架 碳环化合物 芳构化 偶联 

分 类 号：O626[理学—有机化学]