酮肟化合物与酰胺衍生物的合成及光谱学性能研究  

Research on Synthesis and Spectroscopic Properties of a Ketoxime Compound and its Amide Derivative

作　　者：朱鹏 陈艳琴 钱涵 梁芮 李福敏 邵林 杨艳华 ZHU Peng;CHEN Yanqin;QIAN Han;LIANG Rui;LI Fumin;SHAO Lin;YANG Yanhua(School of Chemistry and Chemical Engineering,Kunming University,Kunming,Yunnan,China 650214;Yunnan Key Laboratory of Metal-Organic Molecular Materials and Device,Kunming,Yunnan,China 650214;Physical and Chemical Inspection Center,Dali Institute for Food Control,Dali,Yunnan,China 671000;Chromatographic Analysis Center,Dali Institute for Food Control,Dali,Yunnan,China 671000)

机构地区：[1]昆明学院化学化工学院,云南昆明650214 [2]昆明学院云南省金属有机分子材料与器件重点实验室(筹),云南昆明650214 [3]大理州食品检验检测院理化检验中心,云南大理671000 [4]大理州食品检验检测院色谱分析中心,云南大理671000

出　　处：《昆明学院学报》2023年第3期58-62,112,共6页Journal of Kunming University

基　　金：云南省化学一流本科专业建设项目(无编号);云南省科技厅基础研究专项青年项目(202101AU070060);云南省大学生创新创业训练计划项目(202111393026);昆明学院引进人才科研项目(YJL2008);云南省金属有机分子材料与器件重点实验室(筹)课题一般项目(YNMOMD2212);昆明学院专业学位研究生教学案例建设项目(20202001).

摘　　要：为探讨酮肟化合物及其酰胺衍生物的光谱学性能,采用亲核取代和亲核加成反应制备出具有咔唑基团的酮肟化合物,并通过Beckmann重排反应制备其相应的酰胺衍生物,对合成的化合物进行核磁和红外表征.结果表明,由于结构的变化,相应的酮化合物、酮肟化合物和酰胺化合物光谱学性能不同,且酮肟化合物具备溶剂效应,而酰胺衍生物对溶剂依赖性小.In order to investigate the spectral properties of a ketoxime compound and its amide compound,a ketoxime compound with carbazole groups was prepared by nucleophilic substitution and nucleophilic addition reactions,and its corresponding amide derivative was prepared by Beckmann rearrangement reaction.The synthesized compounds were characterized by nuclear magnetic resonance and infrared spectra.The results showed that the spectral properties of corresponding a ketone compound,ketoxime compound and amide compound were different due to structural changes.And ketoxime compound had solvent effect.However,the corresponding amide derivative had little dependence on solvent.

关 键 词：咔唑基酮肟化合物 BECKMANN重排 酰胺衍生物 光谱学性能 

分 类 号：O626[理学—有机化学] O657.61[理学—化学]