Analysis of the simultaneous adsorption mechanism of ammonium and phosphate on magnesium-modified biochar and the slow release effect of fertiliser  

作　　者：Qingshan He Xiufen Li Yueping Ren 

机构地区：[1]Laboratory of Environmental Biotechnology,School of Environmental and Civil Engineering,Jiangnan University,Wuxi 214122,Jiangsu,People’s Republic of China [2]Jiangsu Key Laboratory of Anaerobic Biotechnology,Wuxi 214122,People’s Republic of China [3]Jiangsu Cooperative Innovation Center of Technology and Material of Water Treatment,Suzhou 215009,People’s Republic of China

出　　处：《Biochar》2022年第1期763-778,共16页生物炭（英文）

基　　金：the National Key Research and Development Project(No.2016YFC0400707);Postgraduate Research and Practice Innovation Program of Jiangsu Provence(No.KYCX17_1453).

摘　　要：To decrease the eutrophication caused by nitrogen(N)and phosphorus(P)in water,magnesium-modified corn stalk biochar(MgB)was prepared under the synergistic impact of the multi-pyrolysis temperatures and Mg^(2+)contents for the co-adsorption of ammonium(NH_(4)^(+)-N)and phosphate(PO_(4)^(3−)).The co-adsorption mechanism,slow-release performance and plant application of MgB were systematically studied.The results showed that pyrolysis temperatures(350-650℃)and Mg^(2+)(0-3.6 g/L)contents not only altered the physicochemical properties of biochar,but also significantly affected the adsorption efficacy of MgB.The adsorption of NH_(4)^(+)-N and PO_(4)^(3−)was in accordance with Langmuir-Freundlich and pseudo-second-order kinetic models(Q_(max)=37.72 and 73.29 mg/g,respectively).Based on the characteristics,adsorption kinetics and isotherms results,the adsorption mechanism was determined and found to mainly involve struvite precipitation,ion exchange,and surface precipitation or electrostatic attraction.Compared with the leaching performance of chemical fertilizers(CF),after adsorption of NH_(4)^(+)-N and PO_(4)^(3−)(MgB-A),MgB had a more stable pH and lower conductivity.Leaching of NH_(4)^(+)-N and PO_(4)^(3−)by MgB-A was controlled by both the diffusion mechanism and the dissolution rate of struvite and Mg-P.The excel-lent long-term slow-release performance and abundant Mg^(2+)of MgB-A promoted the growth of Zea mays L.and Lolium perenne L.Overall,this study suggested that MgB could realize a win-win outcome of struvite biochar-based fertiliser production and wastewater treatment.

关 键 词：AMMONIUM PHOSPHATE Adsorption Magnesium-modified biochar Slow-release fertiliser 

分 类 号：O64[理学—物理化学]