Ni催化NHPI还原活性酯与卤代烃的脱羧偶联反应研究进展  

Recent progress in decarboxylative coupling reaction of NHPI of Ni

作　　者：梁炳玉 路博华 陶乐[1] 李允 李玉江[1] 董黎红[1] 王强[1] 郭晓河[1] 田云飞 LIANG Bingyu;LU Bohua;TAO Le;LI Yun;LI Yujiang;DONG Lihong;WANG Qiang;GUO Xiaohe;TIAN Yunfei(High&New Technology Research Center of Henan Academy of Sciences,Zhengzhou 450002,China;College of Veterinary Medicine and Engineering,Nanyang Vocational College of Agriculture,Nanyang 473000,China;College of Chemistry and Chemical Engineering,Luoyang Normal University,Luoyang 471000,China)

机构地区：[1]河南省科学院高新技术研究中心,河南郑州450002 [2]南阳农业职业学院牧医工程学院,河南南阳473000 [3]洛阳师范学院化学化工学院,河南洛阳471000

出　　处：《南阳师范学院学报》2023年第4期44-49,共6页Journal of Nanyang Normal University

基　　金：河南省科技攻关计划资助项目(232102310380);河南省理化分析测试工程技术中心运行费(231002007);河南省自然科学基金(202300410290);河南省科学院基本科研费项目(220602011,230602007);河南省科技创新杰出青年基金(094100510019);河南省基础与前沿技术研究项目(162300410006)。

摘　　要：随着有机合成方法学的发展,Ni催化偶联反应在众多方面都有了广泛的应用,其中,Ni催化NHPI还原活性酯与卤代烃的脱羧偶联反应越来越受到化学家的关注,本文主要介绍最近几年该领域的最新研究进展和该策略在合成中的应用。With the development of organic synthesis methodology,Ni catalyzed coupling reaction has been widely used in many aspects,among which,Ni catalyzed decarboxylated coupling reaction of NHPI reducing active ester and halogenated hydrocarbon has attracted more and more attention from chemists.This paper mainly introduces the latest research progress in this field in recent years and the application of this strategy in synthesis.

关 键 词：Ni催化 NHPI还原活性酯 卤代烃 脱羧偶联 

分 类 号：O626[理学—有机化学]