蛋白质衍生氮掺杂碳用作电化学能源材料的研究进展  

Research Progress of Protein-derived Nitrogen-doped Carbon Materials as Electrochemical Energy Materials

作　　者：贾少培 宗泳吉 黄权 李其松 张茜 李彩玉 王志新[1] 穆云超[1] JIA Shaopei;ZONG Yongji;HUANG Quan;LI Qisong;ZHANG Qian;LI Caiyu;WANG Zhixin;MU Yunchao(School of Materials and Chemical Engineering,Zhongyuan University of Technology,Zhengzhou 451191,China;School of Electronic and Information,Zhongyuan University of Technology,Zhengzhou 451191,China)

机构地区：[1]中原工学院材料与化工学院,郑州451191 [2]中原工学院电子信息学院,郑州451191

出　　处：《材料导报》2023年第15期216-229,共14页Materials Reports

基　　金：国家自然科学基金(51902358)。

摘　　要：电化学储能和能源转换技术是解决可持续能源与环境问题的重要途径,其电极材料的成本与性能成为规模化应用的关键。氮掺杂碳材料因其独特的物化性质被广泛应用到电化学能源材料中,其中蛋白质衍生氮掺杂碳材料因其原材料丰富、合成简单、环境友好等优点而备受关注,但明晰前驱体和制备工艺对结构性质的影响机制及在应用中的构效关系成为其走向规模化应用的理论基础和关键步骤。本综述调研了近年来蛋白质衍生氮掺杂碳材料用作电化学能源材料的合成与性能情况,先综合分析各类蛋白质衍生碳材料的概况并总结原材料选择的条件;然后分析了不同制备方法及工艺参数对氮掺杂碳材料结构性质的调控和电化学性能提升的作用机制,并详细讨论了蛋白质衍生氮掺杂碳材料在电化学储能和电催化能源转换应用中的构效关系;最后提出蛋白质衍生氮掺杂碳材料在电化学能源材料规模化应用中所要面临的挑战和发展前景。期望本综述有助于新型电化学能源材料的设计开发与应用。Electrochemical energy storage and energy conversion technology is an important way to solve sustainable energy and environmental problems,and the cost and performance of its electrode materials are the key to commercial applications.Nitrogen-doped carbon materials are widely used in electrochemical energy materials because of their unique physical and chemical properties.Protein-derived nitrogen-doped carbon materials have attracted much attention due to their abundant raw materials,simple synthesis and eco-friendly,but the influence mechanism of precursors and preparation process on structure and properties,and the structure-effect relationship in applications still needs to be clearly established,which is the theoretical basis and key step to achieving the large-scale applications.This review investigates the synthesis and perfor-mance data of protein-derived nitrogen-doped carbon materials used as electrochemical energy materials in recent years.Firstly,we summarize the conditions of raw material selection by comprehensively analyzing the data of various protein-derived carbon materials.Then we analyze the influence mechanisms of different preparation methods and process parameters on the structure and performance of nitrogen-doped carbon materials.In addition,we discuss in detail the structure-effect relationship of protein-derived nitrogen-doped carbon materials in electrochemical energy storage and electrocatalytic energy conversion applications.Finally,we present the challenges and development prospects of protein-derived nitrogen-doped carbon materials in the large-scale application of electrochemical energy materials.We expect this review to contribute to the design,development and application of novel electrochemical energy materials.

关 键 词：氮掺杂碳材料 蛋白质 电化学能源装置 储能材料 电催化能源转换材料 

分 类 号：TB34[一般工业技术—材料科学与工程]