应用于气体分离的金属有机骨架成型研究进展  

Review on the shaping of metal-organic frameworks for gas separation

作　　者：李立博[1] 费小龙 刘小华 Li Libo;Fei Xiaolong;Liu Xiaohua(College of Chemical Engineering and Technology,Taiyuan University of Technology,Taiyuan 030024,China)

机构地区：[1]太原理工大学化学工程与技术学院,太原030024

出　　处：《河南师范大学学报（自然科学版）》2023年第5期37-45,F0002,共10页Journal of Henan Normal University(Natural Science Edition)

基　　金：国家自然科学基金(22278287)。

摘　　要：金属有机框架(Metal-organic Framework,MOF)材料是一类由金属离子或团簇与有机配体自组装形成网状结构的多孔材料.因其具有高度可调控的孔道结构和孔表面基团,近年来在气体分离领域表现出优异的性能,受到学术界与工业界的高度关注.然而,一般合成的MOF仅为微米左右,不能直接应用于工业分离过程,因此MOF材料的颗粒成型技术对其工程化应用具有重要意义.对MOF材料的成型方法展开了详细的讨论,并对各类成型方法的适用范围、优劣势及应用场合等方面进行总结及比较,对MOF成型的未来研究方向进行展望.Metal-organic Framework(MOF) is a kind of porous material composed of metal ions or clusters and organic ligands self-assembly to form a network structure.Due to its highly regulated pore structure and pore surface groups,MOF materials have shown excellent performance in the field of gas separation,which is highly concerned by academia and industry in recent years.However,the synthesized MOF is in micron size and cannot be directly applied to industrial separation process.Therefore,the particle forming technology of MOF material is of great significance to its industrial application.In this paper,the shaping methods of MOF materials are discussed in detail,and the application scope,advantages and disadvantages of various molding methods are summarized and compared,and the future research direction of MOF shaping is prospected.

关 键 词：金属有机框架 成型方法 气体分离 

分 类 号：O413[理学—理论物理]