非手性分子介导的聚苯胺超分子手性纳米材料的构筑及应用研究进展  

Research progress in achiral fabrication and application of polyaniline chiral materials

作　　者：周传强 孙晓环 韩杰[1] 郭荣[1] Chuanqiang Zhou;Xiaohuan Sun;Jie Han;Rong Guo(School of Chemistry and Chemical Engineering,Yangzhou University,Yangzhou 225002,China;Testing Center,Yangzhou University,Yangzhou 225009,China)

机构地区：[1]扬州大学化学化工学院,扬州225002 [2]扬州大学测试中心,扬州225009

出　　处：《中国科学：化学》2023年第7期1064-1076,共13页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:22272146,22272147)资助项目。

摘　　要：导电高分子手性纳米材料因其独特的电学、手性光学性质及应用潜力,近年来已经引起了材料化学家的广泛关注.在非手性分子介导的体系中,构筑导电高分子手性纳米材料,有助于加深人们对手性起源的认识,更有利于新型多功能手性纳米材料的开发,具有重要的科学意义和研究价值.本文聚焦非手性分子介导体系,重点介绍了本课题组在聚苯胺手性纳米材料构筑及应用方面的最新研究进展,旨在激发研究者新的研究思路并拓展该材料新的性能和应用.本文最后提出了该研究领域当前所面临的挑战和发展前景.Conductive polymer chiral nanomaterials have attracted wide attentions from material chemists due to their unique electrical and chiroptical properties as well as promising applications.Constructing conductive polymer chiral nanomaterials in achiral system has very important scientific and research significance,because it is not only helpful for human to deeply cognize the chirality origin,but also favorable for scientists to develop novel multi-functional nanomaterials.Based on the design and experimental practice of achiral fabrication systems,this article mainly introduces our research progress in the achiral fabrications of conductive polymer chiral nanomaterials,in order to stimulate new research idea about these nanomaterials and expand novel worthwhile properties and promising applications.Finally,the challenges and prospects for constructing advanced conductive polymer chiral nanomaterials are discussed.

关 键 词：导电高分子 手性纳米材料 无手性制备 超分子手性组装 对映体选择性识别 

分 类 号：O641.3[理学—物理化学] TB383.1[理学—化学]