锂/钾离子电池锑铋基负极材料研究进展  

Recent progress on antimony/bismuth based anodes in lithium/potassium ion batteries

作　　者：常立民[1,2] 候美琪 聂平 程勇[3] CHANG Li-min;HOU Mei-qi;NIE Ping;CHENG Yong(College of Chemistry,Jilin Normal University,Siping 136000,China;Key Laboratory of Preparation and Applications of Environmental Friendly Materials of the Ministry of Education,Jilin Normal University,Changchun 130103,China;State Key Laboratory of Rear Earth Resource Utilization,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China)

机构地区：[1]吉林师范大学化学学院,吉林四平136000 [2]吉林师范大学环境友好材料制备与应用教育部重点实验室,吉林长春130103 [3]中国科学院长春应用化学研究所稀土资源利用国家重点实验室,吉林长春130022

出　　处：《吉林师范大学学报（自然科学版）》2023年第3期1-10,共10页Journal of Jilin Normal University:Natural Science Edition

基　　金：国家重点研发计划项目(2017YFE0198100);吉林省科技发展计划项目(YDZJ202101ZYTS185,202230508046RC)。

摘　　要：由于锂离子电池具有高能量密度和工作电压,几乎成为当前储能市场的最大赢家.然而,锂资源的不均衡分布和高成本制约了其大规模推广和可持续发展.近年来,钾离子电池因其与锂离子电池相似的工作原理而备受关注.在发展高能量密度的二次电池方面,提高电极材料的比容量是关键,而开发低成本、高容量、循环稳定性好的负极材料则具有重要意义.由于其多电子反应机理和高比容量,锑铋基负极材料在二次电池领域得到了广泛的研究.本文首先介绍了锂/钾离子电池的特点、工作原理和合金型负极材料的研究现状,重点总结了近年来锑铋基负极材料在锂/钾离子电池中的研究进展,最后对锑铋基负极未来的发展趋势进行了分析和展望.Lithium-ion batteries are almost the biggest winners in current energy storage market because of their high energy density and operating voltage.However,the uneven distribution and high cost of lithium resources restrict their large-scale application and sustainable development.In recent years,potassium-ion batteries have attracted more and more attention because of their similar working principles with lithium-ion batteries.Improving the specific capacity of electrode materials is the key to the development of high energy density rechargable batteries,and it is of great significance to develop anode materials with low cost,high capacity and good cycle stability.Antimony-bismuth-based anode materials have been widely studied in the field of secondary batteries due to their multi-electron reaction mechanism and high specific capacity.In this review,the characteristics and working principle of lithium/potassium ion batteries and the research status of alloy anode materials were introduced,and the research progress of antimony and bismuth based anode materials in lithium/potassium ion batteries in recent years was summarized.Finally,the possible development trend of antimony and bismuth-based anode in the future was analyzed and prospected.

关 键 词：锑 铋 比容量 锂离子电池 钾离子电池 

分 类 号：O646[理学—物理化学] TM911[理学—化学]