顺酐加氢制备γ-丁内酯催化剂研究进展  

Research progress on catalysts for hydrogenation of maleic anhydride toγ-butyrolactone

作　　者：李太平 张涛 黄家兴 张晓昕 王海京 LI Tai-ping;ZHANG Tao;HUANG Jia-xing;ZHANG Xiao-xin;WANG Hai-jing(SINOPEC Research Institute of Petroleum Processing,Beijing 100080,China)

机构地区：[1]中国石油化工股份有限公司石油化工科学研究院,北京100080

出　　处：《应用化工》2023年第7期2192-2197,2201,共7页Applied Chemical Industry

基　　金：国家自然科学基金(22072182)。

摘　　要：主要综述了近年来顺丁烯二酸酐加氢制备γ-丁内酯催化剂的研究进展,分开阐述了研究者们对Cu系、Ni系以及贵金属系催化剂的研究成果,部分延伸了催化剂在顺丁烯二酸酐加氢制备丁二酸酐以及其衍生物反应中的作用。详细介绍了Cu系催化剂中Cu-Zn系催化剂以及Cu-非Zn系催化剂的优势和缺陷,详细介绍了助剂、载体、催化剂制备方法等因素对于Ni系催化剂加氢性能的影响,介绍了以Pd、Ru系为代表的贵金属催化剂在加氢反应中的优良性能。未来工业化催化剂可通过引入电子型助剂、高温型助剂、多组元活性中心等方式来提高催化剂活性以及稳定性。This article mainly reviews the recent research progress of maleic anhydride to prepareγ-butyrolactone catalysts,and separately expounds the research results of Cu-based catalysts,Ni-based catalysts and noble metal catalysts,and partially extends the role of catalysts in the hydrogenation of maleic anhydride to prepare succinic anhydride and its derivatives.The advantages and disadvantages of Cu-Zn catalysts and Cu-non-Zn catalysts in Cu-based catalysts are introduced in detail,the effects of additives,supports,catalyst preparation methods and other factors on the hydrogenation performance of Ni-based catalysts are introduced in detail,and the excellent performance of noble metal catalysts represented by Pd-based and Ru-based in hydrogenation reaction is introduced.In the future,industrialized catalysts can improve the activity and stability of catalysts by introducing electronic additives,high-temperature additives,and multi-component activity centers.

关 键 词：顺丁烯二酸酐 Γ-丁内酯 加氢催化剂 

分 类 号：TQ225.24[化学工程—有机化工]