低共熔溶剂辅助合成新型的网状纳米结构用于加速甲酸电氧化  

Deep Euteceic Solvents-assisted Synthesis of Novel Network Nanostructures for Accelerating Formic Acid Electrooxidation

作　　者：张俊明 张小杰 陈瑶 房英健 樊友军 贾建峰[1] Jun-Ming Zhang;Xiao-Jie Zhang;Yao Chen;Ying-Jian Fang;You-Jun Fan;Jian-Feng Jia(Key Laboratory of Magnetic Molecules&Magnetic Information Materials Ministry of Education,The School of Chemical and Material Science,Shanxi Normal University,Taiyuan,030031,Shanxi,China;Guangxi Key Laboratory of Low Carbon Energy Materials,College of Chemistry and Pharmaceutical Sciences,Guangxi Normal University,Guangxi,Guilin,541004,China;Kunshan Superior Silk Screen Printing Material Co.,LTD,Kunshan,215300,Jiangsu,China)

机构地区：[1]山西师范大学化学与材料科学学院,磁性分子与磁信息材料教育部重点实验室,山西太原030031 [2]广西师范大学化学与药学学院,广西低碳能源材料重点实验室,广西桂林541004 [3]昆山良品丝印器材有限公司,江苏昆山215300

出　　处：《电化学》2023年第5期32-41,共10页Journal of Electrochemistry

基　　金：supported by the National Nat-ural Science Foundation of China(22162006);the China Postdoctoral Science Foundation(2021M 691366);the Natural Science Foundation of Shanxi Province(20210302124473).

摘　　要：低共熔溶剂(DESs)是一种用于可控合成金属纳米结构的溶剂。在氯化胆碱-尿素DESs中,使用抗坏血酸作为还原剂可以制备由交错的纳米片和纳米球组成的花状Pd纳米颗粒,并且其自发地转化为三维网络纳米结构。此纳米网状结构的形成机制也有系统的研究,其中,DESs作为溶剂和软模板用于形成3D花状钯网络纳米结构(Pd-FNNs),CTAB和NaOH的用量在Pd-FNNs的各向异性生长和生成中起着至关重要的作用。Pd较低的电催化性能是阻碍燃料电池商业化应用的主要挑战之一。然而,具有较低表面能和丰富晶界的3D Pd-FNNs对甲酸氧化反应表现出增强的电催化活性和稳定性,其质量活性和本征活性分别是商业Pd黑催化剂的2.7和1.4倍。因此,此策略为合成独特的Pd基纳米结构提供了一种可行的路径。Deep eutectic solvents(DESs)have been reported as a type of solvent for the controllable synthesis of metal nanostructures.Interestingly,flower-like palladium(Pd)nanoparticles composed of staggered nanosheets and nanospheres are spontaneously transformed into three-dimensional(3D)network nanostructures in choline chlorideurea DESs using ascorbic acid as a reducing agent.Systematic studies have been carried out to explore the formation mechanism,in which DESs itself acts as a solvent and soft template for the formation of 3D flower-like network nanostructures(FNNs).The amounts of hexadecyl trimethyl ammonium bromide and sodium hydroxide also play a crucial role in the anisotropic growth and generation of Pd-FNNs.The low electrocatalytic performance of Pd is one of the major challenges hindering the commercial application of fuel cells.Whereas,the 3D Pd-FNNs with lower surface energy and abundant grain boundaries exhibited the enhanced electrocatalytic activity and stability toward formic acid oxidation,by which the mass activity and specific activity were 2.7 and 1.4 times higher than those of commercial Pd black catalyst,respectively.Therefore,the current strategy provides a feasible route for the synthesis of unique Pdbased nanostructures.

关 键 词：低共熔溶剂 钯 网络纳米结构 甲酸 电氧化 

分 类 号：TB383.1[一般工业技术—材料科学与工程] TQ426[化学工程] TM911.4[电气工程—电力电子与电力传动]