A critical review of vanadium-based electrode materials for rechargeable magnesium batteries  

作　　者：Xiu-Fen Ma Hong-Yi Li Weiwei Ren Daibo Gao Fuyu Chen Jiang Diao Bing Xie Guangsheng Huang Jingfeng Wang Fusheng Pan 

机构地区：[1]College of Materials Science and Engineering,Chongqing University,Chongqing 400044,China [2]National Engineering Research Center for Magnesium Alloys,Chongqing University,Chongqing 400044,China

出　　处：《Journal of Materials Science & Technology》2023年第22期56-74,共19页材料科学技术（英文版）

基　　金：supported by the National Natural Science Foundation of China (Grant Nos.52074050 and 52222407);Chongqing Science and Technology Bureau (Nos.cstc2019jcyjjqX0006 and cstc2021ycjh-bgzxm0075).

摘　　要：Rechargeable magnesium batteries(RMBs)are one of the most promising next-generation energy storage devices due to their high safety and low cost.With a large family and versatile advantageous structures,vanadium-based compounds are highly competitive as electrode materials of RMBs.This review summa-rizes the structural characteristics,electrochemical performance,and refinement methods of vanadium-based materials,including vanadium oxides,vanadium sulfides,vanadates,vanadium phosphates,and vanadium spinel compounds,as RMB cathodes.Although relatively less,vanadium-based materials as RMB anodes are also introduced.According to the application requirements of RMBs,present common strategies are concluded to improve the electrochemical performance of vanadium-based materials;the probably promising development directions are also proposed,which are not limited only to the elec-trode materials,but also the compatible electrolytes and separator materials.In the near future,RMBs are expected from their large-scale application,standing at the forefront of the energy storage era.

关 键 词：Rechargeable magnesium battery Vanadium-based material Cathode ANODE 

分 类 号：TQ125.2[化学工程—无机化工] TM912[电气工程—电力电子与电力传动]