小分子催化转化中的凝聚态化学  

Condensed Matter Chemistry in Catalytic Conversion of Small Molecules

作　　者：王海[1] 王成涛 周航[1] 王亮[1] 肖丰收[1] Hai Wang;Chengtao Wang;Hang Zhou;Liang Wang;Fengshou Xiao(College of Chemical and Biological Engineering,Zhejiang University,Hangzhou 310027,China)

机构地区：[1]浙江大学化学工程与生物工程学院,杭州310027

出　　处：《化学进展》2023年第6期861-885,共25页Progress in Chemistry

摘　　要：催化在现代工业文明中占据极为重要的地位,在炼油、石油化工、精细化工、制药、环境保护等行业中具有主导作用。小分子的催化转化是解决相关能源和环境问题的关键技术,已成为当今国际社会研究的难点与热点之一。本文针对小分子催化转化中的凝聚态化学,讨论了烷烃脱氢、有机小分子加氢、高效产氢以及合成气转化等过程中凝聚态多层次结构对于催化性能的影响,强调了金属-载体之间的相互作用带来的凝聚态化学性质的变化,最后进行总结和展望。希望通过本文可以为凝聚态多层次结构和催化性能之间的构效关系研究提供思路,为今后高效催化剂的进一步开发与机理研究提供指导。Catalysis has played an important role in the modern chemical industry.The processes of oil refining,petrochemical industry,fine chemical industry,pharmaceutical industry,and environmental protection strongly rely on catalysts.The catalytic transformation of small molecules is a key technology that provides solutions for energy and environmental problems,which has become one of the most important and hot topics in the international community.In this article,we summarize the progress of condensed matter chemistry and focus on the catalytic conversion of small molecules.The dehydrogenation of alkanes,hydrogenation of organic small molecules,efficient hydrogen production,and syngas conversion are summarized and discussed.The changes in the chemical properties of the condensed state caused by the metal-support interactions have been emphasized.We hope this review is helpful for the study of the structure-performance relationship between the multi-level structure of condensed matter and their catalytic properties,guiding the design of efficient catalysts in the future.

关 键 词：小分子 多相催化 构效关系 多层次结构 凝聚态化学 

分 类 号：O643[理学—物理化学]