亚临界或超临界反应的凝聚态化学  

Condensate Matter Chemistry of Subcritical or Supercritical Reactions

作　　者：张媛 郑贝宁 吴小峰 黄科科[1] 冯守华[1] Yuan Zhang;Beining Zheng;Xiaofeng Wu;Keke Huang;Shouhua Feng(State Key Laboratory of Inorganic Synthesis and Preparative Chemistry,Jilin University,Changchun 130012,China;College of Physics,Jilin University,Changchun 130012,China)

机构地区：[1]吉林大学无机合成与制备化学国家重点实验室,长春130012 [2]吉林大学物理学院,长春130012

出　　处：《化学进展》2023年第6期968-982,共15页Progress in Chemistry

基　　金：国家自然科学基金项目(No.21831003,22090044);吉林省科技厅项目(No.20200802003GH)资助。

摘　　要：通过化学反应形成确定的和复杂的原子分子凝聚态,其原子分子间相互作用的多维度复合与协同,拓展了物质结构模式,体系性能发生突变,表现出凝聚态化学的某些特性。在特定条件下或在超临界条件下的歧化反应,产生锰金属离子以三种氧化态的形式聚集成的复杂调制结构。本文从凝聚态化学角度出发,详细介绍了在亚/超临界水热条件下,原子尺度pn结固体的生成,量子IV特性与电场诱导超流现象,讨论了化学反应驱动的凝聚态转变问题。本文同时介绍了凝聚态流体的基本性质和各级凝聚尺度中气体分子参与的化学反应,包括化学键修复反应、水热反应、人工降雨和肿瘤的消退,以及超临界条件下凝聚态化学反应的机理和潜在应用。Through chemical reactions,definite and complex atomic and molecular condensed matter is formed.The multi-dimensional composite and synergy of the interactions between atoms and molecules expand the structure pattern of matter,and the properties of the system change dramatically,showing some characteristics of condensed matter chemistry.Under certain conditions or under supercritical disproportionation reaction,manganese metal ions are aggregated into complex modulated structures in the form of three oxidation states.In this paper,from the perspective of condensed matter chemistry,the formation of atomic-scale pn junction solids under subcritical hydrothermal conditions,quantum IV properties and electric field induced superflow phenomenon are introduced in detail,and chemical reaction driven condensed matter transition is discussed.This paper also introduces the basic properties of condensed fluid and chemical reactions involving gas molecules at all levels of condensed scale,including chemical bond repair reaction,hydrothermal reaction,artificial rainfall,tumor regression,as well as the mechanism and potential applications of condensed matter chemical reactions under supercritical conditions.

关 键 词：超临界 水热歧化反应 原子尺度pn结 玻色爱因斯坦凝聚 肿瘤消退 

分 类 号：O6-1[理学—化学] O611