过渡金属催化烯烃和炔烃合成1,3-共轭二烯化合物研究进展  

Research Progress of Transition Metal Catalyzed Synthesis of 1,3-Conjugated Diene Compounds from Alkenes and Alkynes

作　　者：徐光利 许静 徐海东 崔香 舒兴中 Guangli Xu;Jing Xu;Haidong Xu;Xiang Cui;Xingzhong Shu(College of Chemistry&Chemical Engineering,Qinghai Normal University,Xining 810000;College of Chemistry&Chemical Engineering,Lanzhou University,Lanzhou 730000)

机构地区：[1]青海师范大学化学化工学院,西宁810000 [2]兰州大学化学化工学院,兰州730000

出　　处：《有机化学》2023年第6期1899-1933,共35页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(Nos.22071084,22271127)资助项目。

摘　　要：1,3-共轭二烯是许多天然产物和药物的关键结构单元.由于共轭烯烃具有特殊的化学性质,它们在有机合成和材料科学中起着核心作用.目前,1,3-共轭二烯的合成主要是通过过渡金属催化的方法实现,通过该方法科研工作者构建了一系列1,3-二烯骨架,丰富了共轭二烯类化合物的结构多样性,同时也扩展了二烯化合物的应用范围.以过渡金属催化剂的种类不同为主线,分类对1,3-二烯的合成进行了综述,并对其发展前景予以展望.1,3-Conjugated dienes are key structural units of many natural products and drugs.Conjugated alkenes also play a central role in organic synthesis and materials science due to their special chemical properties.At present,the synthesis of 1,3-conjugated diene is mainly achieved by transition metal catalysis,and researchers have constructed a series of 1,3-diene skeletons through this method,which enriches the structural diversity of conjugated diene compounds and extends the application range of diene compounds.The synthesis of 1,3-diene is reviewed by classification based on the different types of transition metal catalysts,and its development prospects are prospected.

关 键 词：过渡金属催化 1 3-共轭二烯 有机合成 应用 

分 类 号：TQ221.22[化学工程—有机化工]