钳形氮杂环卡宾金属络合物的研究进展  

Research Progress on Pincer N-Heterocyclic Carbene Metal Complexes

作　　者：杨亮茹[1] 郭梦丽 袁金伟[1] 王佳美 夏宇婷 肖咏梅[1] 毛璞[1] Yang Liangru;Guo Mengli;Yuan Jinwei;Wang Jiamei;Xia Yuting;Xiao Yongmei;Mao Pu(School of Chemistry and Chemical Engineering,Henan University of Technology,Zhengzhou 450001)

机构地区：[1]河南工业大学化学化工学院,郑州450001

出　　处：《有机化学》2023年第6期2002-2025,共24页Chinese Journal of Organic Chemistry

基　　金：河南省科技厅自然科学基金(No.212102310332);河南省留学人员科技活动择优资助、河南工业大学河南省省属高校基本科研业务费专项基金(No.2017RCJH08);河南工业大学创新基金支持计划专项(No.2020ZKCJ29)资助项目。

摘　　要：氮杂环卡宾作为一类结构和性质特殊且便于调控的新型配体,近年来备受研究者关注.结构多样、性能各异的多种氮杂环卡宾金属络合物也被广泛合成,并被应用于催化、合成、材料、医药等领域.综述了近年来含N、P、S、O、Se等杂原子配位及不同杂化态C的钳形氮杂环卡宾金属络合物的合成及应用研究进展.As a type of novel ligands featuring special structure and properties that can be easily regulated,N-heterocyclic carbenes(NHCs)have attracted much research attention in recent years.Various NHC metal complexes with typical structure and properties have been synthesized and utilized widely in the fields of catalysis,synthesis,materials,pharmaceuticals,etc.Here,recent research progress on the synthesis and applications of pincer NHC metal complexes containing heteroatoms of N,P,S,O,Se,etc.and C featuring different hybrid state is summarized.

关 键 词：氮杂环卡宾 钳形金属络合物 合成 应用 

分 类 号：O641.4[理学—物理化学]