Er掺杂CGA晶体的生长及浓度优化研究  

Growth and Concentration Optimization of Er-Doped CGA Crystals

作　　者：李琳 谭慧瑜 郑为比 谭俊成 李真[1,2] 张沛雄 陈振强 LI Lin;TAN Huiyu;ZHENG Weibi;TAN Juncheng;LI Zhen;ZHANG Peixiong;CHEN Zhenqiang(Department of Optoelectronic Engineering,Jinan University,Guangzhou 510632,China;Guangdong Provincial Engineering Research Center of Crystal and Laser Technology,Guangzhou 510632,China)

机构地区：[1]暨南大学光电工程系,广州510632 [2]广东省晶体与激光技术工程研究中心,广州510632

出　　处：《人工晶体学报》2023年第7期1325-1334,共10页Journal of Synthetic Crystals

基　　金：国家自然科学基金(51972149,61935010,51872307,51702124,62175091);广东省重点领域研究发展计划(2020B0090922006)。

摘　　要：本文采用激光加热基座法生长出一系列掺杂不同Er^(3+)浓度(摩尔分数)的Er∶CaGdAlO 4(Er∶CGA)激光晶体,并对制备出的系列晶体开展详细的光学性能研究。结合J-O理论计算和光学性能表征,通过对比吸收光谱中780~840和955~1020 nm的最大吸收系数、吸收截面、半峰全宽和辐射寿命等,以及荧光发射光谱的发射强度、发射截面和能级荧光寿命等光学性能参数,得到Er^(3+)的最佳掺杂浓度为5%。该工作为获得一种有望用于1.5~1.7μm近红外波段全固态激光器的新型激光增益介质提供了一定的实验基础。In this paper,a series of Er∶CaGdAlO 4(Er∶CGA)laser crystals with different Er^(3+)doping concentrations(molar fraction)were grown by laser-heated pedestal growth method.The optical properties of the prepared series crystals were studied in detail.The maximum absorption coefficient,absorption cross section,full width at half maximum and radiation lifetime at the range of 780~840 and 955~1020 nm in the absorption spectra were compared by combining the J-O theoretical calculation and optical characterization.In addition,the optical performance parameters of fluorescence emission spectrum such as emission intensity,emission cross section and energy level fluorescence lifetime were characterized and futher calculated.As a result,the optimal doping concentration of Er^(3+)is 5%.This work provides a certain experimental basis for obtaining a new type of laser gain medium which is expected to be used in 1.5~1.7μm near-infrared band all-solid-state laser.

关 键 词：1.5~1.7μm近红外激光 Er∶CGA晶体 激光加热基座法 光学性能 全固态激光器 增益介质 

分 类 号：O782[理学—晶体学]