阳离子田菁胶助染剂对纸浆纤维染色效果的影响  

Effect of Cationic Sesbania Gum Dyeing Assistance on Pulp Fiber Dyeing

作　　者：韩继友 潘思宇 梁任华 杨仁党[2] HAN Jiyou;PAN Siyu;LIANG Renhua;YANG Rendang(Minfeng Special Paper Co.,Ltd.,Jiaxing,Zhejiang Province,314000;State Key Lab of Pulp and Paper Engineering,South China University of Technology,Guangzhou,Guangdong Province,510640)

机构地区：[1]民丰特种纸股份有限公司,浙江嘉兴314000 [2]华南理工大学制浆造纸工程国家重点实验室,广东广州510640

出　　处：《中国造纸》2023年第6期32-39,共8页China Pulp & Paper

摘　　要：为实现无盐染色,本实验引入阳离子田菁胶作为助染剂,通过增强染料与纸浆纤维间的吸附作用,经济环保地提高了浆内染色效果。结果表明,阳离子田菁胶作为直接耐晒翠兰(GL)染料的助染剂效果良好。光学显微镜与扫描电子显微镜观察表明GL染料、纸浆纤维、阳离子田菁胶结合紧密。通过单因素实验探究阳离子田菁胶用量、染色温度、染液pH值对纸浆纤维染色效果的影响,确定了最佳助染工艺条件为:阳离子田菁胶用量0.2%,染色温度45℃,染液pH值3,该条件下上染率可达92.6%。建立染色吸附动力学模型和染色吸附等温线可知,染色时间对染色效果影响较小,适当提高染液初始浓度可有效提高染色效果。To achieve salt-free dyeing,this study introduced cationic sesbania gum as a dyeing assistance to improve the in-pulp dyeing effect by enhancing the adsorption between the dye and pulp fibers.The results showed that cationic sesbania gum was effective as a dye⁃ing assistance for GL dye.Optical microscopy and SEM showed that the GL dye,pulp fibers,and cationic sesbania gum were tightly bound.The effect of pH value,temperature,and cationic sesbania gum dosage on the dyeing effect of pulp fibers was investigated by sin⁃gle-factor experiments,and the optimal dyeing conditions were determined as follows:cationic sesbania gum dosage 0.2%,pH value of dyeing solution 3,dyeing temperature 45℃,and the dye uptake reached 92.6%under this condition.The dyeing adsorption kinetic model and dyeing adsorption isotherm were established,showing that the dyeing time had negligible effect on dyeing effect,which could be effectively improved by appropriately increasing the initial concentration of dyeing solution.

关 键 词：阳离子田菁胶 助染剂 浆内染色 染色效果 

分 类 号：TS727.7[轻工技术与工程—制浆造纸工程]