由芘衍生的手性单硼酸荧光探针对手性二胺类化合物的手性识别  

Chiral Recognition of Pyrene-derived Chiral Monoboronic Acid Fluorescent Probes for Chiral Diamines

作　　者：邹佳音 马珂 李晨锋 刘萌 张欣[1] ZOU Jiayin;MA Ke;LI Chenfeng;LIU Meng;ZHANG Xin(College of Chemistry and Materials Science,Hebei Normal University,Hebei Key Laboratory of Organic Functional Molecules,Hebei Shijiazhuang 050024,China)

机构地区：[1]河北师范大学化学与材料科学学院,河北省有机功能分子重点实验室,河北石家庄050024

出　　处：《河北师范大学学报（自然科学版）》2023年第5期483-492,共10页Journal of Hebei Normal University：Natural Science

基　　金：国家自然科学基金(21502040);河北省自然科学基金(B201620511);河北省大学生创新创业训练计划项目(S202310094009)。

摘　　要：对由芘衍生的手性单硼酸探针R1和S1进行了手性二胺的对映选择性识别测试.结果表明,在L酒石酸的诱导下,R1在2种不同溶剂体系中对手性二胺类化合物均有显著的识别能力;S1对手性二胺类化合物也显示出一定的手性识别效果.The enantioselective recognition behaviors for chiral diamines with two pyrene-derived chiral monoboronic acid fluorescent probes R-1 and S-1 in two different solvent systems were investigated.The results showed that in the presence of L-tartaric acid,R-1 exhibited significant chiral recognition behaviors for the chiral diamines in two different solvent systems,and S-1 also showed certain chiral recognition effect for the chiral diamines.

关 键 词：对映选择性识别 手性二胺类化合物 芘 手性荧光探针 

分 类 号：O62[理学—有机化学]