游离氨预处理污泥促进有机物释放过程研究  

Study on promotion of organic matters release through pretreatment of sludge by free ammonia

作　　者：沈嘉辉 王侃宏 梁玉帅 郁达伟[1,3] 魏源送[1,3] SHEN Jia-hui;WANG Kan-hong;LIANG Yu-shuai;YU Da-wei;WEI Yuan-song(Water Pollution Control Laboratory,Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085,China;School of Energy and Environmental Engineering,Hebei University of Engineering,Handan 056038,China;State Key Joint Laboratory of Environment Simulation and Pollution Control,Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing 100085,China)

机构地区：[1]中国科学院生态环境研究中心水污染控制实验室,北京100085 [2]河北工程大学能源与环境工程学院,河北邯郸056038 [3]中国科学院生态环境研究中心,环境模拟与污染控制国家重点联合实验室,北京100085

出　　处：《现代化工》2023年第7期104-112,共9页Modern Chemical Industry

基　　金：国家自然科学基金面上项目(52170062);国家重点研发计划(2016YFD0501405)。

摘　　要：针对污泥厌氧消化水解阶段有机物释放受限、影响产甲烷的问题,通过优化游离氨预处理的剂量,考察了不同游离氨预处理浓度、持续时间下,污泥水解阶段的有机物释放效果。结果表明,与控制组相比,优化剂量的游离氨处理后TCOD、SCOD质量浓度分别提高了134.64%~250.34%、154.70%~274.55%,表明优化的游离氨水平有效强化了污泥的预处理效果。组分分析结果表明,溶解性蛋白质、多糖浓度分别提高111.70%、412.37%,VS水解率增加16.60%~80.38%。三维荧光光谱(3D-EEM)的PARAFAC分析表明,游离氨预处理后提高了生物可降解有机物占比,主要以溶解性微生物副产物(41.18%)、类酪氨酸(29.32%)为主;同时促进难降解有机物的转化。不同于高能耗预处理的强力溶胞破壁,以温和调节的游离氨预处理方式强化水解,可提高液相中溶解性有机物质量浓度,进而改善污泥中有机物释放效果。In order to solve the problems of limited release in sludge anaerobic digestion hydrolysis stage and affecting methane production,the dosage of free ammonia for pretreatment is optimized,and the release effect of organic matters in sludge hydrolysis stage is investigated under different concentration and duration of free ammonia pretreatment.It is shown that compared with the control group,the mass concentrations of TCOD and SCOD increase by 134.64%-250.34%and 154.70%-274.55%,respectively after the dosage of free ammonia is optimized,meaning that the optimized free ammonia level enhances the pretreatment effect of sludge effectively.The results from component analysis show that the concentrations of soluble protein and polysaccharide increase by 111.70%and 412.37%,respectively,and the hydrolysis rate of VS increases by 16.60%-80.38%.PARAFAC analysis based on 3D fluorescence spectroscopy shows that the pretreatment by free ammonia increases the proportion of biodegradable organic matters,which mainly include soluble microbial byproducts(41.18%)and tyrosines(29.32%).Meanwhile,the conversion of refractory organic matter is promoted.Different from pretreatment by high energy consumption method such as strong cell lysis and wall breaking,the hydrolysis is enhanced by gently regulated free ammonia pretreatment to improve the mass concentration of dissolved organic matters in the liquid phase,thus improving the release effect of organic matters in sludge.

关 键 词：游离氨 预处理 水解阶段 有机物释放 生物降解性 

分 类 号：X703.1[环境科学与工程—环境工程]