丙烯高温氯化反应研究与反应器设计优化  

Research on propylene high-temperature chlorination reaction and optimization of reactor design

作　　者：刘利 LIU Li(Sinopec Hunan Petrochemical Resin Department Epoxy Resin Department,Yueyang 414003,China)

机构地区：[1]中石化湖南石化树脂部环氧树脂部,湖南岳阳414003

出　　处：《中国氯碱》2023年第8期23-30,共8页China Chlor-Alkali

摘　　要：介绍了氯丙烯现有生产工艺,比较了3种主流工艺的主要优缺点和经济技术指标,分析了丙烯高温氯化反应机理与反应动力学,并针对典型反应器进行了CFD模拟,提出了改进方向,设计了全新射流式反应器,并开展了工业应用研究。This paper briefly introduced the existing production processes of allyl chloride,compared the main advantages and disadvantages of the three main processes,and analyzed the mechanism and chemical kinetics of high temperature chlorination of allyl chloride,CFD simulation was carried out for typical reactors,the improvement direction was proposed,a new jet reactor was designed,and the industrial application research was carried out.

关 键 词：3-氯丙烯 高温氯化 CFD模拟 喷嘴 射流式反应器 

分 类 号：TQ222.424[化学工程—有机化工]