Copper-Catalyzed Three-Component Azidotrifluoromethylation/Difunctionalization of Alkenes  

作　　者：Mingbo Yang Wenlu Wang Yin Liu Lijie Feng Xuexia Ju 

机构地区：[1]Gansu Research Institute of Chemical Industry,Lanzhou,Gansu 730020,China [2]Gansu Province Environmental Monitoring Center,Lanzhou,Gansu 730020,China

出　　处：《Chinese Journal of Chemistry》2014年第9期833-837,共5页中国化学（英文版）

基　　金：We thank the Gansu Province Key Laboratory of Fine Chemical(No.1206RTSA022);the Gansu Province Science and Technology Innovation Service Platform Construction Plan(No.1306TTPA024)for financial support.We also acknowledge support from the Gansu Province Containing Fluorine Meticulous Chemicals R&D Platform Project and Program for Pharmaceutical Intermediates Innovation Research Team in Gansu Province(No.1207TTCA009).

摘　　要：A novel three-component strategy for the azidotrifluoromethylation of alkenes has been presented here.The reaction proceeded smoothly under gentle temperature and gave the bifunctional olefins in high yields.Furthermore,1,3-dipolar reactions between azide-containing products and phenylacetylene revealed great potential in molecular modification by using this method.

关 键 词：azidotrifluoromethylation ALKENES azide-containing 

分 类 号：O62[理学—有机化学]