Aniline Induced Domino Ring Contraction Process on the Rim of an Open-Cage Fullerene with Carbonyl, Imino and lactone Moieties  

作　　者：Shuming Liu Liangbing Gan 

机构地区：[1]Beijing National Laboratory for Molecular Sciences,CAS Key Laboratory for Organic Solids,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China [2]Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China [3]State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Shanghai 200032,China [4]Key Laboratory of Small Organic Molecule of Handan,College of Chemistry,Chemical Engineering and Materials,Handan College,Handan,Hebei 056005,China

出　　处：《Chinese Journal of Chemistry》2014年第8期819-821,共3页中国化学（英文版）

基　　金：the National Natural Science Foundation of China(Nos.21272013 and 21132007);the Major State Basic Research Development Program(No.2011CB808401).

摘　　要：Functional groups on the rim of open-cage fullerenes usually exhibit different reactivity from those in classical organic molecules due to the unique spherical structure of fullerenes.The present work shows a sequence of lactone opening,imino hydrolysis,aminal formation and imine formation processes during the reaction of aniline with the open-cage compound 1 with functional groups including lactone on the rim of the orifice.Single crystal X-ray diffraction analysis confirmed the structure of the product.

关 键 词：FULLERENE open-cage fullerene ring contraction molecular container 

分 类 号：O62[理学—有机化学]