醇解法制备生物基化学品乙酰丙酸酯的研究进展  

Research progress on preparation of biomass-based alkyl levulinate by alcoholysis

作　　者：张晶阳 张为宏 郑晓阳 阎振丽 赵子高 常春[1,4] ZHANG Jing-yang;ZHANG Wei-hong;ZHENG Xiao-yang;YAN Zhen-li;ZHAO Zi-gao;CHANG Chun(School of Chemical Engineering,Zhengzhou University,Zhengzhou 450001,China;Henan Huakang Sugar Alcohol Technology Co.,Ltd.,Jiaozuo 454150,China;State Key Laboratory of Vehicle Biofuel Technology,Nanyang 473000,China;Henan Center for Outstanding Overseas Scientists,Zhengzhou 450001,China)

机构地区：[1]郑州大学化工学院,河南郑州450001 [2]焦作市华康糖醇科技有限公司,河南焦作454150 [3]车用生物燃料技术国家重点实验室,河南南阳473000 [4]河南省杰出外籍科学家工作室,河南郑州450001

出　　处：《现代化工》2023年第8期44-48,53,共6页Modern Chemical Industry

基　　金：国家自然科学基金项目(22178328);河南省科技攻关项目(222102320059);南阳市协同创新重大专项(郑州大学南阳研究院)项目(21XTCX12002)。

摘　　要：综述了近年来醇解法制备乙酰丙酸酯的研究进展,分别对生物质直接醇解法、糠醇醇解法和其他原料醇解法进行了总结,重点对催化剂和反应体系的研究进展进行了综述,并对醇解法制备生物基乙酰丙酸酯进行了展望。Latest progress in the preparation of alkyl levulinate by alcoholysis is reviewed.Summarization is performed to direct biomass alcoholysis,furfuryl alcohol alcoholysis and other raw materials alcoholysis.The research progress on catalyst and reaction system is mainly reviewed,and the preparation of bio-based alkyl levulinates by alcoholysis is prospected.

关 键 词：乙酰丙酸酯 生物质 醇解法 催化剂 反应体系 

分 类 号：TQ225.24[化学工程—有机化工]