机械-水热联合法制备高活性硅酸二钙  

Preparation of Highly Reactive Dicalcium Silicate by Mechano Hydrothermal Processing

作　　者：杨正宏[1,2] 何翠兰 李祯 李博 徐玲琳[1,2] YANG Zhenghong;HE Cuilan;LI Zhen;LI Bo;XU Linglin(School of Materials Science and Engineering,Tongji University,Shanghai 201804,China;Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education,Tongji University,Shanghai 201804,China)

机构地区：[1]同济大学材料科学与工程学院,上海201804 [2]同济大学先进土木工程材料教育部重点实验室,上海201804

出　　处：《建筑材料学报》2023年第7期816-822,共7页Journal of Building Materials

基　　金：国家自然科学基金资助项目(52172022);同济大学大型仪器开放测试基金项目(2022GX010)。

摘　　要：以稻壳灰和Ca(OH)_(2)为原料,B2O3为稳定剂,通过机械-水热联合法制备了高活性硅酸二钙(C_(2)S),研究了预处理工艺对稻壳灰活性以及烧成制度对硅酸二钙活性的影响.结果表明:稻壳灰经1%稀硫酸溶液预处理2.5 h后煅烧,可使稻壳灰活性增高,有利于提高水热合成的效率;分段煅烧和掺入0.5%的B_(2)O_(3)促进了β-C_(2)S的形成,并提升了其早期水化活性,有利于强度发展;按钙硅比为2配制的物料经球磨2.0 h、水热4.0 h后,先在500℃下预烧1.0 h,再升温至600℃煅烧1.0 h,可得到高活性硅酸二钙,其水化7、28 d后的抗压强度分别为33.0、41.1 MPa.Highly reactive dicalcium silicate was prepared by mechano‑hydrothermal processing using rice husk ash and Ca(OH)_(2)as raw materials,and B_(2)O_(3)as stabilizer.The effects of pretreatment process on the activity of rice husk ash and calcination system were studied.The results show that the rice husk ash is highly activated by pretreating with 1%dilute sulfuric acid solution for 2.5 h and calcining,which favors to the efficiency improvement of hydrothermal synthesis.Both annealing and addition of 0.5%B_(2)O_(3)contribute to the formation ofβ‑C_(2)S and enhance its early hydration activity,which is beneficial to the strength development.The optimum procedure is ball‑milling for 2.0 h,then hydrothermal condition for 4.0 h,followed by preheating at 500℃for 1.0 h,and finally calcining at 600℃for 1.0 h.The compressive strength of highly reactive dicalcium silicate reaches 33.0 MPa and 41.1 MPa after 7 d and 28 d of curing,respectively.

关 键 词：稻壳灰 硅酸二钙 水化活性 机械-水热联合法 

分 类 号：TU528[建筑科学—建筑技术科学]