One-Pot Synthesis of Aliphatic Nitro Compounds by Michael/retro-Claisen Fragmentation Domino Reaction  

作　　者：Wei Zhang Yanjing Wang Cuibing Bai Jialong Wen Naixing Wang 

机构地区：[1]Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,Beijing 100190,China [2]College of Sciences,Beijing University of Chemical Technology,Beijing 100029,China

出　　处：《Chinese Journal of Chemistry》2015年第4期401-404,共4页中国化学（英文版）

基　　金：supported financially by the National Natural Science Foundation of China(21172227).

摘　　要：A novel and concise method for the construction ofγ-nitro ketones and 1,3-dinitro compounds with chemo-selective acyl transfer has been presented under basic conditions via one-pot reactions.These reactions feature high atom-and step-economic possess,mild condition and simple operation for one-pot synthesis of aliphatic nitro compounds.This protocol provides the products in good yields.The possible reaction mechanism has also been proposed.

关 键 词：γ-nitro ketones 1 3-dinitro compounds chemoselective acyl transfer domino reaction atom-and step-economies 

分 类 号：O62[理学—有机化学]