Synthesis of Coumarin-Pillar[5]arene as a Selective Fluorescent Probe for Methyl-Parathion  

作　　者：Fan Zhang Xianliang Cao Demei Tian Haibing Li 

机构地区：[1]Key Laboratory of Pesticide and Chemical Biology of the Ministry of Education,College of Chemistry,Central China Normal University,Wuhan,Hubei 430079,China

出　　处：《Chinese Journal of Chemistry》2015年第3期368-372,共5页中国化学（英文版）

基　　金：supported by the National Natural Science Foundation of China(Nos.21372092,21102051);the Natural Science Foundation of Hubei Province(Nos.2013CFA112,2014CFB246);the Self-determined Research Funds of CCNU from the Colleges Basic Research and Operation of MOE(Nos.CCNU13F005,CCNU14Z01001).

摘　　要：A novel coumarin-pillar[5]arene derivative(P5C10)was prepared.Fluorescence spectroscopy indicates that P5C10 shows good selectivity towards methyl-parathion.A combination of NMR spectra,MALDI-TOF spectra and computational calculations reveals the formation of a host-guest complex driven byπ-πstacking interactions.

关 键 词：fluorescent probe arene methyl-parathion HOST-GUEST 

分 类 号：O62[理学—有机化学]