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作 者:黎然 陈龙 刘刚[2] 张宇 黎雪 邓夏蕊 Li Ran;Chen Long;Liu Gang;Zhang Yu;Li Xue;Deng Xiarui(Engineering Technology Research Institute of Petrochina Southwest Oil and Gas Field Company,Chengdu 610017,Sichuan,China;CCDC Chuanxi Drilling Company,Chengdu 610041,Sichuan,China)
机构地区:[1]中石油西南油气田公司工程技术研究院,四川成都610017 [2]中石油川庆钻探工程有限公司川西钻探公司,四川成都610041
出 处:《精细石油化工》2023年第5期65-69,共5页Speciality Petrochemicals
基 金:中石油西南油气田分公司科研项目(20200302-11)。
摘 要:分析了四川盆地蓬莱气区钻井酸性气体来源,并导致钻井液流变性变差的原因。相同区块不同钻井液体系在老化后,有机盐聚合物钻井液在100℃热滚2 d钙离子分别从1160、1100 mg/L降至280、0 mg/L,表明有机盐聚合物钻井液中有二氧化碳产生。对钻井液材料的热滚和稳定性测试发现,在150℃钻井液单剂老化过程中钻井液用降滤失剂羧羟基烷烯共聚物(L)有明显的酸性气体产生,且磺化钻井液体系材料的二氧化碳产生量明显小于聚合物材料。对材料进行MS-DC分析可知,L产生的二氧化碳的总的量较多;钻井液用降滤失剂阳离子小分子聚合物(YLZ)等抗温性相对较差,并在160℃开始分解。The frequent invasion of acidic gases during drilling in the Penglai gas field of the Sichuan Basin leads to poor rheological properties of the drilling fluid.A series of studies have been conducted to identify the source of acidic gases in the drilling fluid.Research have found that after aging of different drilling fluid systems in the same block,the calcium ions in the organic salt polymer drilling fluid decreased from 1160 and 1100 mg/L to 280 and 0 mg/L,respectively,after hot rolling at 100℃for 2 days,indicating that the production of carbon dioxide in the organic salt polymer drilling fluid.According to the thermal rolling and stability tests of drilling fluid materials,during the single agent aging process of drilling fluid at 160℃,reagents such as L(carboxyl hydroxyalkylene copolymer)produce significant acidic gases.The carbon dioxide production of sulfonated drilling fluid system materials was significantly lower than that of polymer materials.According to the MS-DC analysis of the material,L produces the largest total amount of carbon dioxide.YLZ(cationic small molecular polymer as a fluid loss additive for drilling fluid)has relatively poor temperature resistance and begins to decompose at 150℃.
分 类 号:TE25[石油与天然气工程—油气井工程]
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