聚4-甲基-1-戊烯的制备及应用进展  

PROGRESS IN THE POIYMERIZATION AND APPLICATION OF POLY(4-METHYL-1-PENTENE)

作　　者：杜文博 刘洋[1] 高建树 刘振宇[1] 蒋文军[1] 梁胜彪[1] Du Wenbo;Liu Yang;Gao Jianshu;Liu Zhenyu;Jiang Wenjun;Liang Shengbiao(Research Institute of Maoming Branch Co.,SINOPEC,Maoming 525011,Guangdong,China)

机构地区：[1]中国石油化工股份有限公司茂名分公司研究院,广东茂名525011

出　　处：《精细石油化工》2023年第5期76-80,共5页Speciality Petrochemicals

摘　　要：介绍了聚(4-甲基-l-戊烯)(PMP)制备以及其应用研究进展情况。根据不同的金属催化活性中心对催化剂进行分类概述;包括齐格勒-纳塔催化剂、茂金属催化剂、非茂金属催化剂、后过渡金属催化剂,指出了PMP工业化生产的最佳催化剂为齐格勒-纳塔催化体系。此外对PMP聚合物的结晶性质以及聚合物的应用进展进行概述,对PMP聚合物的国产化发展进行评述和展望。The research progress in the preparation and application of PMP were introduced.Firstly,catalysts were classified based on different metal catalytic active centers,including Ziggler-Natta catalysts,metallocene catalysts,non-metallocene catalysts,and late transition metal catalysts.By comparison,the best catalyst for industrial production of PMP is the Ziegler-Natta catalytic system.In addition,the crystallization performance of the PMP and the application progress of the polymer were also summarized.Finally,a review and discussion were conducted on the development of domestically produced PMP polymers.

关 键 词：催化剂 聚(4-甲基-1-戊烯) 结晶树脂 配位聚合 

分 类 号：TQ325.1[化学工程—合成树脂塑料工业]