利用CO_(2)和无机硫源电化学构建C-S键  

Electrochemical C-S bond construction from CO_(2) and an inorganic sulfur source

作　　者：吴永萌 赵静辉 张兵 Yongmeng Wu;Jinghui Zhao;Bin Zhang(Department of Chemistry,Institute of Molecular Plus,School of Science,Tianjin University,Tianjin 300072,China)

机构地区：[1]Department of Chemistry,Institute of Molecular Plus,School of Science,Tianjin University,Tianjin 300072,China

出　　处：《Science Bulletin》2023年第14期1466-1468,共3页科学通报（英文版）

基　　金：the National Postdoctoral Science Foundation of China(2022M722357)to Y.W.for financial support。

摘　　要：Constructing C–S bonds is important in pharmaceuticals,agriculture,biology,optoelectronic materials and battery technologies[1–3].At present,several strategies have been established in organic synthetic chemistry,such as sulfa-Michael addition[4],allylic or methane sulfonation[5],and Diels-Alder reactions[6].Although continuous advances have been made,the sustainable implementation of these methods is limited by complicated synthetic procedures,toxic solvents and byproducts,and scalability restrictions.Therefore,developing an alternative strategy to achieve the sustainable construction of C–S bonds under ambient conditions,especially from inexpensive and abundant inorganic reactants,is highly desirable。

关 键 词：BONDS reactant AMBIENT 

分 类 号：O641.1[理学—物理化学]