烯烃羰基化反应非均相催化剂研究进展  

Research Progress in Heterogeneous Catalysts forOlefin Carbonylation Reaction

作　　者：李丹 童杨 LI Dan;TONG Yang(High Tech Research and Development Center of the Ministry of Science and Technology,Beijing 100044,China)

机构地区：[1]科学技术部高技术研究发展中心,北京100044

出　　处：《化工管理》2023年第27期153-164,共12页Chemical Engineering Management

摘　　要：近年来烯烃羰基化反应得到快速发展,羰基化产品丰富,应用领域也逐渐推广。为解决实际工业应用问题,传统的均相催化剂逐步向多相催化技术转型。文章综述了烯烃羰基化非均相催化剂研究进展,介绍了水-有机两相催化剂体系,详述单原子催化剂、合金催化剂、双金属催化剂以及均相催化剂多相化研究进展,为烯烃羰基化领域提出催化设计指导。In recent years,the olefin carbonylation reaction has been developed rapidly,the carbonylation products are abundant,and the application fields are gradually promoted.In order to solve the problem of practical industrial application,the traditional homogeneous catalyst is slowly transforming to heterogeneous catalytic technology.In this paper,the research progress of heterogeneous catalysts for olefin carbonylation is reviewed.The water-organic two-phase catalyst system is introduced.The research progress of single atom catalyst,alloy catalyst,bimetallic catalyst and homogeneous catalyst is described in detail.

关 键 词：烯烃羰基化 两相催化 非均相催化 单原子催化剂 合金催化剂 

分 类 号：TQ224[化学工程—有机化工]