2,2'-双(4-(3-氨基苯氧基)苯基)六氟丙烷的合成与表征  

Synthesis and Characterization of 2,2'-bis(4-(3-Aminophenoxy)Phenyl)Hexafluoropropane

作　　者：张浩 马德龙 李剑波 赵振伟 樊明如 Zhang Hao;Ma Delong;Li Jianbo;Zhao Zhenwei;Fan Mingru(Shandong Yanggu Huatai Chemical Co.,Ltd.,Liaocheng 252300,China)

机构地区：[1]山东省阳谷华泰化工股份有限公司,山东聊城252300

出　　处：《山东化工》2023年第16期34-37,共4页Shandong Chemical Industry

摘　　要：在强极性非质子有机溶剂中,以双酚AF、间氯硝基苯和无水碳酸钾为原料,通过取代缩合反应制备得到2,2'-双(4-(3-硝基苯氧基)苯基)六氟丙烷(BNPHP),再以Pd/C为催化剂,H_(2)为还原剂,将2,2'-双(4-(3-硝基苯氧基)苯基)六氟丙烷还原,得到2,2'-双(4-(3-氨基苯氧基)苯基)六氟丙烷(BAPHP),2,2'-双(4-(3-氨基苯氧基)苯基)六氟丙烷的最终收率98.8%,纯度在99%以上。2,2'-bis(4-(3-nitrophenylate)phenyl)1hexafluoropropane was prepared by substituted condensation reaction with hexafluorobisphenol A,m-chloronitrobenzene and anhydrous potassium carbonate in a strong polar aprotic organic solvent.And then,using Pd/C as catalyst and H_(2)as reducing agent,2,2'-bis(4-(3-nitrophenoxy)phenyl)hexafluoropropane was reduced to 2,2'-bis(4-(3-aminophenoxy)phenyl)hexafluoropropane(BAPHP).The final yield of 2,2'-bis(4-(3-aminophenoxy)phenyl)hexafluoropropane was 98.8%,and the purity was more than 99%.

关 键 词：2 2'-双(4-(3-硝基苯氧基)苯基)六氟丙烷 聚酰亚胺单体 催化还原 2 2'-双(4-(3-氨基苯氧基)苯基)六氟丙烷 

分 类 号：TQ242[化学工程—有机化工]