甲醚化三聚氰胺甲醛树脂聚合程度对橡胶黏合性能的影响  

Effect of Polymerization Degree of Methyletherized Melamine Formaldehyde Resin on Rubber Adhesion

作　　者：孟庆勇 孟祥克 王才朋 李文革 张朋龙 徐思明 陈庆兵 温以亮 朱金伟 Meng Qingyong;Meng Xiangke;Wang Caipeng;Li Wenge;Zhang Penglong;Xu Siming;Chen Qingbing;Wen Yiliang;Zhu Jinwei(National Engineering Technology Research Center for Rubber,Shandong Yanggu Huatai Chemical Co.,Ltd.,Yanggu 252300,China)

机构地区：[1]山东阳谷华泰化工股份有限公司国家橡胶助剂工程技术研究中心,山东阳谷252300

出　　处：《山东化工》2023年第15期65-69,共5页Shandong Chemical Industry

摘　　要：使用六羟甲基三聚氰胺(HMM)与甲醇进行反应,通过改变物料配比和反应条件,制备了5批次不同聚合程度的甲醚化三聚氰胺甲醛树脂,并使用高效液相色谱、凝胶色谱、理化性质分析等方式进行表征。将制备的甲醚化三聚氰胺甲醛树脂与白炭黑混料,分别作为黏合剂制备胶料,并考察不同聚合程度的甲醚化三聚氰胺甲醛树脂在黏合胶料配方中的应用效果差异。Five batches of methyletherized melamine formaldehyde resin with different polymerization degree were prepared by using hexahydroxymethyl melamine resin(HMM)to react with methanol and changing the material ratio and reaction conditions.High performance liquid chromatography,gel chromatography and physicochemical property analysis were used for characterization.The prepared methyl ether melamine formaldehyde resin and white carbon black were mixed as adhesives to prepare rubber compound.The difference of application effect of methyletherized melamine formaldehyde resin with different degree of polymerization in adhesive formulation was investigated.

关 键 词：氨基树脂 甲醚化 聚合程度 应用效果 

分 类 号：TQ326.5[化学工程—合成树脂塑料工业]