含碳氟类底物参与的羰基化反应研究进展  

Progresses on Fluorocarbon-Containing Substrates Involved Carbonylation Reactions

作　　者：安大列 包志鹏 吴小锋 AnDa-Lie;Bao Zhi-Peng;WuXiao-Feng(Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023;University of Chinese Academy of Sciences,Beijing 101408)

机构地区：[1]中国科学院大连物理化学研究所,大连116023 [2]中国科学院大学,北京101408

出　　处：《有机化学》2023年第7期2304-2312,共9页Chinese Journal of Organic Chemistry

摘　　要：含氟有机分子的合成和转化已蓬勃发展成为氟化学重要的前沿课题之一,它深刻地影响着生命科学和材料科学.其中碳氟化合物参与的羰基化反应是近几年发展起来的一类羰基化反应,它拥有诸多的挑战.介绍了过渡金属钯、镍和铜催化的碳氟化合物参与的羰基化反应研究进展.为了理解这些反应的历程,也选择了一些具有代表性的反应介绍其反应机理.The synthesis and transformation of fluorine-containing organic molecules has experienced vigorously development and has become one of the most important frontier topics of fluorine chemistry,which profoundly affects life science and material science.Among them,carbonylative transformation of fluorocarbon-containing substrates is a carbonylation reaction developed in recent years which still has many challenges.This review summarized the progresses on fluorocarbon-containing substrates carbonylation reactions based on transition metal palladium,nickel and copper catalysis.In order to understand the mechanism of these reactions,representative reactions were selected for detailed discussion.

关 键 词：碳氟化合物 羰基化反应 过渡金属 

分 类 号：O621.25[理学—有机化学]