微波法合成荧光酮及其荧光性质研究  

Synthesis of Fluorone by Microwave Method and Its Fluorescence Properties

作　　者：叶思彤 张帆 崔亮霞 王宁芳 刘丽敏[1] 张广昊 YE Si-tong;ZHANG Fan;CUI Liang-xia;WANG Ning-fang;LIU Li-min;ZHANG Guang-hao(School of Chemical Engineering,Anhui University of Science&Technology,Huainan 232001,China)

机构地区：[1]安徽理工大学化学工程学院,安徽淮南232001

出　　处：《安徽化工》2023年第4期58-63,共6页Anhui Chemical Industry

基　　金：安徽理工大学省级大学生创新创业训练计划项目(S202110361170);安徽省重点研究与开发计划项目(202004h07020022)。

摘　　要：以间苯二酚、苯甲醛(水杨醛)为原料,对甲苯磺酸为催化剂,采用微波加热法与传统方法合成化合物A和化合物B,并比较了两种方法的优缺点。通过正交实验方法探索了微波功率、加热时间、催化剂用量对反应产率的影响,同时探讨了pH值和溶剂对产品光物理性质的影响。Compound A and compound B were synthesized by microwave heating method and traditional method using resor⁃cinol and benzaldehyde(salicylic aldehyde)as raw materials and p-toluenesulfonic acid as catalyst.The effects of micro⁃wave power,heating time and catalyst dosage on the reaction yield were preliminarily studied.Orthogonal experiments were used to explore the optimal reaction conditions.The influence of pH value and solvent on photophysical properties was also discussed.

关 键 词：荧光酮 微波辐射法 荧光性质 光物理性质 

分 类 号：TQ251[化学工程—有机化工]