Zinc–Bromine Rechargeable Batteries:From Device Configuration,Electrochemistry,Material to Performance Evaluation  

作　　者：Norah S.Alghamdi Masud Rana Xiyue Peng Yongxin Huang Jaeho Lee Jingwei Hou Ian R.Gentle Lianzhou Wang Bin Luo 

机构地区：[1]Australian Institute for Bioengineering and Nanotechnology(AIBN),The University of Queensland,Brisbane,QLD 4072,Australia [2]School of Chemistry and Molecular Biosciences,Faculty of Science,The University of Queensland,Brisbane,QLD 4072,Australia [3]School of Chemical Engineering,The University of Queensland,Brisbane,QLD 4072,Australia [4]Department of Chemistry,Faculty of Science,Imam Mohammad Ibn Saud Islamic University(IMSIU),11564 Riyadh,Saudi Arabia

出　　处：《Nano-Micro Letters》2023年第11期349-384,共36页纳微快报（英文版）

基　　金：flnancial support from Australian Research Council through its Discovery,Future Fellowship Programs;Imam Mohammad Ibn Saud Islamic University (IMSIU) in Riyadh,Saudi Arabia,for flnancial support of this work.

摘　　要：Zinc–bromine rechargeable batteries(ZBRBs)are one of the most powerful candidates for next-generation energy storage due to their potentially lower material cost,deep discharge capability,non-flammable electrolytes,relatively long lifetime and good reversibility.However,many opportunities remain to improve the efficiency and stability of these batteries for long-life operation.Here,we discuss the device configurations,working mechanisms and performance evaluation of ZBRBs.Both non-flow(static)and flow-type cells are highlighted in detail in this review.The fundamental electrochemical aspects,including the key challenges and promising solutions,are discussed,with particular attention paid to zinc and bromine half-cells,as their performance plays a critical role in determining the electrochemical performance of the battery system.The following sections examine the key performance metrics of ZBRBs and assessment methods using various ex situ and in situ/operando techniques.The review concludes with insights into future developments and prospects for high-performance ZBRBs.

关 键 词：Zinc–bromine rechargeable batteries Cell configurations Electrochemical property Performance metrics Assessment methods 

分 类 号：TM912[电气工程—电力电子与电力传动]