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机构地区:[1]School of Metallurgy,Northeastern University,Shenyang 110819,China [2]Key Laboratory for Ecological Metallurgy of Multimetallic Ores(Ministry of Education),Northeastern University,Shenyang 110819,China
出 处:《Journal of Rare Earths》2023年第9期1459-1466,I0007,共9页稀土学报(英文版)
基 金:supported by the National Natural Science Foundation of China-Liaoning Joint Fund (U1908224)。
摘 要:The quality of stainless steel is closely related to the deformability of inclusions,which is significantly affected by their compositions.The present study first inve stigated the evolution of inclusion compositions in AI-killed steel with rare earth-alkali metals(Ca or Mg)combined treatme nt through four laboratory-scale experiments.The Ce contents in the final steel are 0.0080 wt%,0.015 wt%,0.016 wt%and 0.010 wt%,respectively.The Mg content is 0.0014 wt%in Ce-Mg combined treated steel,and the Ca content is0.0015 wt%in Ce-Ca combined treated steel.The deformability of inclusions in both Ce_(2)O_(3)-Al_(2)O_(3)-CaO and Ce_(2)O_(3)-Al_(2)O_(3)-MgO systems was subsequently evaluated by calculating their Young's modulus at low temperature.The results show that irregular Al_(2)O_(3)and MgAl_(2)O_(4)with poor deformability are modified to CeAlO_(3)and Ce_(2)O_(3)by Ce treatment,resulting in the decrease of Young's modulus of inclusions.The deformability of inclusions is further improved due to the transformation from lumped-like CeAlO_(3)to spherical CaO-Al_(2)O_(3)-Ce_(2)O_(3)caused by Ca treatment,and some of these inclusions are the ones with low liquidus temperature.Thermodynamic analysis was used to discuss the control condition of the formation and evolution of inclusions.Accordingly,the appropriate addition amounts of Al,Mg,Ce,and Ca are expected to control inclusion compositions and properties,including deformability and liquidus temperature,thereby improving the steel performance.
关 键 词:Rare earths Alkali metals Inclusions evolution Inclusions deformability Thermodynamic analysis
分 类 号:TG142.1[一般工业技术—材料科学与工程]
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